首页> 外国专利> Decontamination of wastewater discharged in a basin of sewage plant and containing harmful cationic metals and organic pollutants, comprises introducing polysaccharide sodium alginate in the basin, and complexing metal cations in the basin

Decontamination of wastewater discharged in a basin of sewage plant and containing harmful cationic metals and organic pollutants, comprises introducing polysaccharide sodium alginate in the basin, and complexing metal cations in the basin

机译:对污水处理厂排放的废水进行净化处理,其中包含有害的阳离子金属和有机污染物,包括在废水池中引入多糖藻酸钠和在废水池中络合金属阳离子

摘要

The process comprises introducing polysaccharide sodium alginate derived from alginic acid having a high proportion of L-guluronic acid blocks of fixed percentage in the basin for diluting the waste water, complexing metal cations in the basin with alginate ions, and mechanically collecting chelates (26) or macromolecules suspended in water to obtain purified water. Each cation forms a covalent bond with an anionic oxygen radical of a polysaccharide alginate monomer. Each divalent cation forms two covalent bonds with two oxygen radicals of two monomers such as G alginates. The process comprises introducing polysaccharide sodium alginate derived from alginic acid having a high proportion of L-guluronic acid blocks of fixed percentage in the basin for diluting the waste water, complexing metal cations in the basin with alginate ions, and mechanically collecting chelates (26) or macromolecules suspended in water to obtain purified water. Each cation forms a covalent bond with an anionic oxygen radical of a polysaccharide alginate monomer. Each divalent cation forms two covalent bonds with two oxygen radicals of two monomers such as G alginates of two different polysaccharides of alginate for naturally forming a chelate or insoluble macromolecule, which is constituted of a three-dimensional structure of polymers constituted of polysaccharides bridged by divalent cations between which the organic pollutants are physically sequestered. The chelates are collected from the surface of the basin water using a scraping device. The collected chelates are subjected to an ion reversibility reaction to form sludge containing cationic metals separated from alginate monomers, alginate, water and organic pollutants released by the ion reversibility reaction. The collected chelates are mixed with a fixed agent causing the ion reversibility reaction during the separation step. The determined agent is constituted of a potassium, magnesium and/or saturated sodium solution and sodium chloride solution. The sludge containing cationic metals is dried, burned and then released during the separation for extracting the water by evaporation to obtain maximum dryness of the sludge. The process further comprises degreasing wastewater from a feeding channel, cleaning and screening during which separating sand, mud, gravel and ash from waste water, sedimenting by agglomerating suspended solids in sub-steps of coagulation and flocculation or flotation during which injecting pressurized air into the waste water to move the solids to the surface and then extracting, biologically treating the waste water, cleaning the treated water, and releasing the treated water in a natural medium. The polluted water is modified by immersing a flow of waste water in a porous container containing a specific quantity of alginate. The specified percentage of sodium alginate introduced in the diluted wastewater is proportional to the concentration of metals contained in the wastewater. An independent claim is included for an arrangement for decontamination of wastewater discharged in a basin of a sewage plant.
机译:该工艺包括将来自比例较高的L-古洛糖醛酸嵌段比例较高的海藻酸的藻酸多糖海藻酸钠稀释到废水中,将海藻酸根离子与海藻酸金属离子络合以及机械收集螯合剂(26)或大分子悬浮在水中以获得纯净水。每个阳离子与多糖藻酸盐单体的阴离子氧自由基形成共价键。每个二价阳离子与两个单体例如藻酸G的两个氧自由基形成两个共价键。该工艺包括将来自比例较高的L-古洛糖醛酸嵌段比例较高的海藻酸的藻酸多糖海藻酸钠稀释到废水中,将海藻酸根离子与海藻酸金属离子络合以及机械收集螯合剂(26)或大分子悬浮在水中以获得纯净水。每个阳离子与多糖藻酸盐单体的阴离子氧自由基形成共价键。每个二价阳离子与两个单体的两个氧自由基形成两个共价键,例如两个不同藻酸盐多糖的G藻酸盐,以自然形成螯合物或不溶性大分子,其由聚合物的三维结构构成,该聚合物由被二价桥连的多糖构成阳离子之间物理隔离的有机污染物。使用刮擦装置从水池水的表面收集螯合物。使收集的螯合物进行离子可逆反应,以形成含有阳离子金属的污泥,所述阳离子金属与通过离子可逆反应释放的藻酸盐单体,藻酸盐,水和有机污染物分离。收集的螯合物与固定剂混合,在分离步骤中引起离子可逆反应。所确定的试剂由钾,镁和/或饱和钠溶液和氯化钠溶液组成。将含有阳离子金属的污泥干燥,燃烧,然后在分离过程中释放出来,以通过蒸发提取水以获得最大的污泥干度。该方法还包括对进料通道中的废水进行脱脂,清洁和筛分,在此过程中将废水中的沙子,泥,砾石和灰分分离出来,在凝结和絮凝或浮选的子步骤中通过将悬浮的固体凝聚而沉淀下来,在此过程中将加压空气注入到废水将固体移至表面,然后进行提取,对废水进行生物处理,清洗处理后的水,然后将处理后的水释放到天然介质中。通过将废水流浸入装有一定量藻酸盐的多孔容器中,可以对污水进行改性。稀释废水中引入的海藻酸钠的指定百分比与废水中所含金属的浓度成正比。包括对污水处理厂水池中排放的废水进行净化处理的一项独立权利要求。

著录项

  • 公开/公告号FR2939425A1

    专利类型

  • 公开/公告日2010-06-11

    原文格式PDF

  • 申请/专利权人 ROBERT JEAN PHILIPPE;

    申请/专利号FR20080058344

  • 发明设计人 ROBERT JEAN PHILIPPE;

    申请日2008-12-08

  • 分类号C02F9/04;

  • 国家 FR

  • 入库时间 2022-08-21 18:26:41

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