Way of extension olefin metathesis polymerization reaction pot life of

摘要

(57) Abstract This application the catalyst does the speed of the orehuinmetaseshisu reaction which includes the opening ring metaseshisu polymerization (ROMP) reaction, it is the composition in order to control and something which states method, the aforementioned composition contains the ruthenium or osmium carbene complex and the gelation adjustment additive which are displayed with formula (i). In formula, M is something which can be Os or Ru, R and R¹ being identical, even when are possible to differ, hydrogen or C₂ - C₂₀ arukeniru, C₂ - C₂₀ arukiniru, C₁ - C₂₀ alkyls, aryl and C₁ - C₂₀ karubokishireto, C₁ - C₂₀ alkoxy, C₂ - C₂₀ arukeniruokishi, C₂ - C₂₀ arukiniruokishi, the aryl oxy and C₂ - C₂₀ alkoxy carbonyl, C₁ - C it is the substituent which includes₂₀ alkyl thio, C₁ - C₂₀ alkyl sulfonyl and C₁ - C₂₀ alkyl sulfinyl,It is something which you obtain, X and X¹ being identical, even when is possible to differ, it is something which can be the anionic characteristic ligand, it is something to which and L and L¹ being identical, even when are possible, can be the neutral electron donor to differ. The gelation adjustment additive, phosphine and sulfonation phosphine, hosuhuaito, phosphine knight (phosphinite) and phospho knight (phosphonite), is something which can be the neutral electron donor or the neutral Lewis base which includes the arsine, stibine, ether, amine, amide, sulfoxide, carboxyl, nitrosyl, pyridine or thioether or is something which can be toriarukiruhosuhuin or thoria reel phosphine.