首页> 外国专利> METHOD FOR PREPARING TRANSITION METAL COMPLEXES, TRANSITION METAL COMPLEXES PREPARED USING THE METOD, CATALYST COMPOSITION CONTAINING THE COMPLEXES

METHOD FOR PREPARING TRANSITION METAL COMPLEXES, TRANSITION METAL COMPLEXES PREPARED USING THE METOD, CATALYST COMPOSITION CONTAINING THE COMPLEXES

机译:制备过渡金属配合物的方法,使用金属的方法制备过渡金属配合物,包含该配合物的催化剂组合物

摘要

The present invention provides a novel transition metal complex where a monocyclopentadienyl ligand to which an amido group is introduced is coordinated, a method for synthesizing the complex, and olefin polymerization using the same. The method for preparing a transition metal complex according to the present invention comprises a step of blocking a by-reaction of a nitrogen atom using a compound containing a protecting group, and thus it is possible to prepare a transition metal complex in a simpler manner in a high yield. Further, the transition metal complex according to the present invention has a pentagon ring structure having an amido group connected by a phenylene bridge in which a stable bond is formed in the vicinity of a metal site, and thus, sterically monomers can easily approach the transition metal complex.
机译:本发明提供了新颖的过渡金属配合物,其中引入了酰胺基的单环戊二烯基配体被配位,合成该配合物的方法,以及使用该配合物的烯烃聚合。根据本发明的制备过渡金属配合物的方法包括使用含有保护基的化合物阻断氮原子的副反应的步骤,因此可以以更简单的方式制备过渡金属配合物。高产量。此外,根据本发明的过渡金属络合物具有五边环结构,该五边形环结构具有通过亚苯基桥连接的酰胺基,其中在金属位点附近形成稳定的键,因此,空间单体可以容易地接近过渡。金属络合物。

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