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SYNTHETIC PHYLLOSILICATES NOT CAPABLE OF SWELLING FOR POLYMER PHYLLOSILICATE (NANO)COMPOSITES
SYNTHETIC PHYLLOSILICATES NOT CAPABLE OF SWELLING FOR POLYMER PHYLLOSILICATE (NANO)COMPOSITES
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机译：合成塑料藻酸酯不适合用于聚合物（甲基丙烯酸钠）复合材料的溶胀
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摘要
The present invention relates to a process for the production of non-swellable phyllosilicate tactoids, comprisingA) producing a synthetic smectite of the formula I in a high-temperature-melt synthesis; [Mn/Valenz]inter[MImMIIo]oct [MIII4]tet X10Y2 (I)B) if the interlayer cation M does not already have a hydration enthalpy from −6282 to −406 [kJ/mol], exchanging the interlayer cation M with a cation having a hydration enthalpy from −6282 to −406 [kJ/mol] by a cation-exchange method,C) dispersing phyllosilicate in an aqueous system, andD) exchanging M with a cation having a hydration enthalpy from −405 to 0 [kJ/mol], by a cation-exchange method.展开▼
机译：本发明涉及生产不可溶胀的层状硅酸盐触针的方法，包括 A）在高温熔融合成中产生式I的合成蒙脱石 ; <？in-line-formulae description =“在线表达式” end =“ lead”？> [M n / Valenz ] inter [M I < / Sup> m M II o ] oct [M III 4 ] tet X 10 Y 2 （I）<？in-line-formulae description =“在线表达式” end =“ tail”？> B）如果层间阳离子M还没有从-6282到-406 [kJ / mol]的水合焓，则将层间阳离子M与具有水合作用的阳离子交换 C），将阳离子硅酸盐在−6282至−406 [kJ / mol]之间的焓降低， ListItem> D）通过阳离子交换方法将M与具有从-405到0 [kJ / mol]的水合焓的阳离子交换。
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