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SYNTHESIS AND CHARACTERIZATION OF AMINE TERMINATED CYCLOALIPHATIC SUBSTITUTED POLYSILOXANES

机译:胺封端的环脂族取代的聚硅氧烷的合成与表征

摘要

The present invention relates to novel amine terminated cycloaliphatic polysiloxanes, and preparations thereof. More particularly, the invention provides several reaction schemes for the synthesis of amino-functionalized cyclo-aliphatic silicones and the products produced by the reaction schemes. In one embodiment of the invention, an amine functionalized silicone is prepared through a base-catalyzed ring-opening reaction. In another embodiment of the invention, an amine functionalized silicone is prepared through the hydrosilation of a silicone oligomer through the blocking and deblocking of an amine terminated in a vinyl group.
机译:本发明涉及新颖的胺封端的环脂族聚硅氧烷及其制备。更特别地,本发明提供了几种用于合成氨基官能化的环脂族硅氧烷的反应方案以及由该反应方案产生的产物。在本发明的一个实施方案中,通过碱催化的开环反应制备胺官能化的硅氧烷。在本发明的另一个实施方案中,胺官能化的硅氧烷是通过硅酮低聚物的氢化硅烷化,通过封端和解封以乙烯基封端的胺来制备的。

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