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PROCESSES FOR THE PRODUCTION OF TRI-ORGANO-MONOALKOXYSILANES AND PROCESS FOR THE PRODUCTION OF TRI-ORGANO-MONOCHLOROSILANES
PROCESSES FOR THE PRODUCTION OF TRI-ORGANO-MONOALKOXYSILANES AND PROCESS FOR THE PRODUCTION OF TRI-ORGANO-MONOCHLOROSILANES
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机译：三有机单氧杂环丁烷的生产工艺和三有机单氯硅氧烷的生产工艺
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摘要
A silane containing a bulky hydrocarbon group or groups R therein and having the formula (III); R3−(x+y)(R1)x(R2)ySi(OR3);can be produced by reacting a silane of the formula (I); (R1)x(R2)ySiCl3−(x+y)(OR3);with a Grignard reagent of the formula (II); RMgX;Further, a tri-organo-chlorosilane of the formula (XIIa); (R1)(R2)(R3)SiCl;can be produced by reacting a tri-organo-silane of the formula (XIa); (R1)(R2)(R3)SiZ1 ;with hydrochloric acid.;Furthermore, a tri-organo-monoalkoxysilane of the formula (XXIII); R3−(x+y)(R1)x(R2)ySi(OR3);can be produced when a silane of the formula (XXI); (R1)x(R2)ySiCl4−(x+y) ;is reacted with a Grignard reagent of the formula (XXII); RMgX;with addition of and reaction with an alcohol or an epoxy compound during the reaction.
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机译：一种其中含有大体积烃基或R基团并具有式（III）的硅烷; <？in-line-formulae description =“在线公式” end =“ lead”？> R 3-（x + y）（R 1 ） x （R 2 ） y Si（OR 3 ）<？in-line-formulae description =“在线可以通过使式（I）的硅烷反应来制备式“ end ＝” tail”？ <？in-line-formulae description =“ In-line Formulae” end =“ lead”？>（R 1 ） x （R 2 ） y SiCl 3-（x + y）（OR 3 ）<？in-line-formulae description =“在线公式“ end =” tail“？>;用式（II）的格氏试剂; <？in-line-formulae description =“ In-line Formulae” end =“ lead”？> RMgX <？in-line-formulae description =“ In-line Formulae” end =“ tail”？>;此外，一个三-式（XIIa）的-有机氯硅烷; <？in-line-formulae description =“ In-line Formulae” end =“ lead”？>（R 1 ）（R 2 ）（R 3 ）SiCl <？in-line-formulae description =“ In-line Formulae” end =“ tail”？>;可以通过使式（XIa）的三有机硅烷反应来制备; <？in-line-formulae description =“ In-line Formulae” end =“ lead”？>（R 1 ）（R 2 ）（R 3 ）SiZ 1 <？in-line-formulae description =“ In-line Formulae” end =“ tail”？>;含盐酸。;此外，三有机单烷氧基硅烷式（XXIII）; <？in-line-formulae description =“在线公式” end =“ lead”？> R 3-（x + y）（R 1 ） x （R 2 ） y Si（OR 3 ）<？in-line-formulae description =“在线当式（XXI）的硅烷时，可以产生式“ end ＝” tail”？ <？in-line-formulae description =“ In-line Formulae” end =“ lead”？>（R 1 ） x （R 2 ） y SiCl 4-（x + y） <？in-line-formulae description =“ In-line Formulae” end =“ tail”？>;已反应用式（XXII）的格氏试剂; <？in-line-formulae description =“ In-line Formulae” end =“ lead”？> RMgX <？in-line-formulae description =“ In-line Formulae” end =“ tail”？>;加上和反应期间与醇或环氧化合物反应。
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