首页> 外国专利> OPTICALLY ACTIVE DINICKEL COMPLEX AND METHOD FOR PRODUCING OPTICALLY ACTIVE AMINE USING THE OPTICALLY ACTIVE DINICKEL COMPLEX AS CATALYST

OPTICALLY ACTIVE DINICKEL COMPLEX AND METHOD FOR PRODUCING OPTICALLY ACTIVE AMINE USING THE OPTICALLY ACTIVE DINICKEL COMPLEX AS CATALYST

机译:光学活性的镍络合物及使用该光学活性的镍络合物作为催化剂生产光学活性的胺的方法

摘要

There is provided a novel optically active dinickel complex and/or a production method of an optically active amine by an asymmetric Mannich reaction using the dinickel complex as a catalyst. An optically active dinickel complex of Formula (I) or Formula (I′):; ;[where R0, R1, R2, R3, R4, R5, R6, and R7 are each independently a hydrogen atom, a halogen atom, a C1-10 alkyl group or a C1-10 alkoxy group, etc., R2 and R3 together form, together with a benzene ring bonded to them, a naphthalene ring, etc. A novel production method of an optically active amine by an asymmetric Mannich reaction using the dinickel complex as a catalyst.
机译:提供了一种新型的光学活性二镍配合物和/或使用二镍配合物作为催化剂通过不对称曼尼希反应的光学活性胺的制备方法。式(I)或式(I')的光学活性二镍配合物: ; [其中R 0 ,R 1 ,R 2 ,R 3 ,R 4 ,R 5 ,R 6 和R 7 分别独立地为氢原子,卤素原子,C 1 -10 烷基或C 1-10 烷氧基等,R 2 和R 3 一起形成一种新的光学活性胺的制备方法,该方法通过使用二镍配合物作为催化剂,通过不对称的曼尼希(Mannich)反应制备旋光性胺。

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