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Process for synthesis of telechelic urethane acrylate UV curable pre-polymeric materials

机译:远螯螯合的聚氨酯丙烯酸酯可紫外线固化的预聚物材料的合成方法

摘要

The present invention involves the design of a radiation curable organic pre polymer resin material based on urethane acrylic linkage synthesized from the natural renewable resource cardanol or a derivative thereof, for coating application. These new molecules have a faster and better curing rate compared to the starting renewable resource—cardanol. This is brought about by the hydrogen bonding of the urethane linkage which leads to a pre organization of the molecules in such a way as to bring the cross linkable double bonds closer to each other. The present invention also involves a UV curable formulation of the above mentioned resins along with 2-10 parts by weight of a photopolymerization initiator. The resin, either in a formulation or alone turns into a cross linked film upon photopolymerization in presence of photoinitiator under a UV curable radiation source like a mercury vapor pressure lamp.
机译:本发明涉及基于氨基甲酸酯丙烯酸酯键的可辐射固化的有机预聚物树脂材料的设计,该材料由天然可再生资源腰果酚或其衍生物合成,用于涂料。与起始的可再生资源腰果酚相比,这些新分子具有更快,更好的固化速度。这是由氨基甲酸酯键的氢键引起的,该氢键导致分子的预组织,从而使可交联的双键彼此靠近。本发明还涉及上述树脂的UV可固化制剂以及2-10重量份的光聚合引发剂。在光引发剂的存在下,在可紫外固化的辐射源(如汞蒸气压力灯)下,在光引发剂的作用下,光聚合时,树脂无论是配方还是单独变成交联膜。

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