首页> 外国专利> Use of aqueous solutions of low viscosity stabilizing flexible polyurethane foams of hot cure containing polyether for producing flexible polyurethane foams hot curing.

Use of aqueous solutions of low viscosity stabilizing flexible polyurethane foams of hot cure containing polyether for producing flexible polyurethane foams hot curing.

机译:使用含有聚醚的低粘度稳定热固化软质聚氨酯泡沫塑料水溶液来生产热固性聚氨酯泡沫塑料。

摘要

aqueous solution of low viscosity stabilizing the flexible polyurethane foams hot curing having a viscosity 5000 mPa.s at 25 ° C, usable for the production of flexible polyurethane foams of hot cure, characterized in that the aqueous solution- low viscosity stabilizing the flexible foams of poly U-Retano hot curing it comprises the components listed below: = 40% by weight to = 70% by weight of polyethersiloxane, = 0.5% to = 20% by weight of an organic surfactant, = 10% by weight of water, = 0% by weight of organic solvent additives, in which the polyethersiloxane has the following formula (I): R1-Si (CH3) 2O - [Si (CH3) (OSi (CH3) 2R0) O-] u- [Si (OSi (CH3) 2R0) 2 O-] v- [Si (CH3) 2O] w- [SiCH3R2O] x- [SiCH3R3O- ] y- [SiCH3R4O] z- [SiR3R4O] t-Si (CH3) 2-R5 in which are: R0 = -O- [Si (CH3) 2O] w- [SiCH3R2O-] x- [SiCH3R3O-] y- [SiCH3R4O] z-Si (CH3) 2-R R1, R2, R3, R4 and R5, same or different from each other in each case, alkyl or aryl moiety of 1 to 12 carbon atoms or in each case -CH 2 -R 6 or -CH 2 -CH 2 R 6 or po (alkylene oxide) -poliéter of Formu -CmH2mO (C2H4O) a (C3H6O) b ( C4H8O) c (C2H3O-C6H5) d (C12H24O) GR7 (II), = H, C6H5, -CN, C1 to C10, -CH-CH2O (epoxide ring), alkyl-OH, -aryl-OH , -Cl, -OH, -R8-O-R9, -R8-O-CO-R9 or divalent bridging link to a moiety if-loxano additional lease selected from the group R8-, -R8-COO-R9-OOC- R8-, -R8-OOC-COO-R9-R8-, R7 = H rest, alkyl, acyl, acetyl or aryl, alkyl aryl or urethane divalent bridging link to an additional siloxane moiety selected from alkylene, -R COR9, - R8-O-R9-oR R8 = alkyl or aryl, R9 = alkyl or ar u = 0 to 5, v = 0 to 5, t = 0 to 15, w = 15 to 130, x = 0 up to 15, y = 0-15, z = 0-15, m = 0 to 4, a = = 0 to = 160, b = = 0 to = 140 c = = 0 to = 50, g = = 0 to = 50, d = = 0 to = 50 where a + b + c + d + g = 10, with the proviso that x + y + z + t = 3, and that at least one R1, R2, R3, R4, R5 substituent is a polyether according to formula II, wherein the weight ratio of the above components is selected such that the total weight ratio of components not exceeds 100% by weight, based flexible polyurethane Espas hot curing.
机译:低粘度稳定柔性聚氨酯泡沫的水溶液在25°C时的粘度<5000 mPa.s,可用于生产热固化柔性聚氨酯泡沫,其特征在于,低粘度水溶液可稳定柔性泡沫聚U-Retano热固性涂料包含以下组分:> = 40%重量至<= 70%重量的聚醚硅氧烷,> = 0.5%至<= 20%重量的有机表面活性剂,> = 10%其中,聚醚硅氧烷具有下式(I):R1-Si(CH3)2O-[Si(CH3)(OSi(CH3)2R0)O- ] u- [Si(OSi(CH3)2R0)2 O-] v- [Si(CH3)2O] w- [SiCH3R2O] x- [SiCH3R3O-] y- [SiCH3R4O] z- [SiR3R4O] t-Si( CH3)2-R5其中:R0 = -O- [Si(CH3)2O] w- [SiCH3R2O-] x- [SiCH3R3O-] y- [SiCH3R4O] z-Si(CH3)2-R R1,R2 ,R 3,R 4和R 5,在每种情况下,彼此相同或不同,碳原子数为1至12的烷基或芳基部分e -CH 2 -R 6或-CH 2 -CH 2 R 6或式的po(环氧烷)-CmH2mO(C2H4O)a(C3H6O)b(C4H8O)c(C2H3O-C6H5)d(C12H24O)GR7 (II),= H,C 6 H 5,-CN,C 1至C 10,-CH-CH 2 O(环氧环),烷基-OH,-芳基-OH,-Cl,-OH,-R 8 -O-R 9,-R 8- O-CO-R9或与部分if-loxano额外租借基团的二价桥接链接,该租约选自组R8-,-R8-COO-R9-OOC-R8-,-R8-OOC-COO-R9-R8-,R7 = H rest,烷基,酰基,乙酰基或芳基,烷基芳基或氨基甲酸酯二价桥接连接至选自亚烷基,-R COR9,-R 8 -O-R 9 -o R的另外的硅氧烷部分R 8 =烷基或芳基,R 9 =烷基或芳基u = 0至5,v = 0至5,t = 0至15,w = 15至130,x = 0至15,y = 0-15,z = 0-15,m = 0至4,a => = 0至<= 160,b => = 0至<= 140 c => = 0至<= 50,g => = 0至<= 50,d => = 0至<= 50其中a + b + c + d + g> = 10,条件是x + y + z + t> = 3,并且至少一个R1,R2,R3,R4,R5取代基是根据式II的聚醚,其中上述成分的重量比选择s使得组分的总重量比不超过100重量%,基于柔性聚氨酯Espas热固化。

著录项

  • 公开/公告号ES2353139T3

    专利类型

  • 公开/公告日2011-02-25

    原文格式PDF

  • 申请/专利权人 EVONIK GOLDSCHMIDT GMBH;

    申请/专利号ES20070787893T

  • 发明设计人 LANDERS RUDIGER;DE GANS BEREND-JAN;

    申请日2007-07-25

  • 分类号C08J9/00;C08K5/00;C08L83/12;

  • 国家 ES

  • 入库时间 2022-08-21 18:02:46

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