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TRIDENTATE LIGANDS AND RELATIVE COMPLEXES WITH TRANSITION METALS

机译:过渡金属的三价配位体和相对络合物

摘要

A description follows of ligands having general formula (I) wherein R~1, R~2,R~3, R~4, R~5, and R~6, the same or different, are selected form hydrogen,halogen, C~1-C~10 alkyl, C~6-C~15 aryl optionally halogenated, or adjacentpairs of R~i groups (with i ranging from 1 to 6) are bound to each other togive cyclic hydrocarbon structures condensed with the thiophene or pyridinering; R~7 is selected from H, C~1-C~10 alkyl, C~6-C~15 aryl; R~8 is selectedfrom C~1-C~10 alkyl and C~6-C~15 aryl. The complexes of the above ligands withtransition metals are also described.
机译:以下描述具有通式(I)的配体,其中R 1,R 2,从氢中选择相同或不同的R〜3,R〜4,R〜5和R〜6,卤素,C〜1-C〜10烷基,C〜6-C〜15芳基(可选被卤化或相邻)对R〜i组(i的范围为1至6)彼此绑定为生成与噻吩或吡啶缩合的环状烃结构环; R 7选自H,C 1至C 10烷基,C 6至C 15芳基;选择R〜8C 1 -C 10烷基和C 6 -C 15芳基。上述配体与还描述了过渡金属。

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