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COMPOSITES OF ZINC PHTHALOCYANINE AND TITANIUM OXIDE, FOR USE IN PHOTOCATALYTICAL PROCESSES, AND METHOD FOR THEIR OBTENTION

机译:用于光催化过程的邻苯二甲酸酞菁锌和二氧化钛的复合物及其制备方法

摘要

The composites object of this invention are catalysts for photochemical processes which aims the environmental decontamination, being their characteristic a very superior photocatalytical efficiency when compared with the observed for pure titanium oxides. The composites, object of the invention, are a combination of TiO2 with a photosensitiser dye, capable to mediate photocatalytical processes using the incident radiation in wavelength ranges incapable to promote the excitation of the pure photocatalyst. This occurs due to the electronic excitation of the dye in these regions of the electromagnetic spectrum. The excited photosensitiser dye promotes electron transfer to the conduction band of the catalyst, potencializing the photocatalytical action. With this, the wastewater treatment with the use of solar radiation becomes interesting, due to the captation of useful photons in a large range of the electromagnetic spectrum and energy conversion from these composites.
机译:本发明的复合材料的目的是用于环境净化的光化学方法的催化剂,与纯钛氧化物相比,其特征是非常优异的光催化效率。本发明的复合材料是TiO 2与光敏染料的组合,其能够使用不能促进纯光催化剂激发的波长范围内的入射辐射来介导光催化过程。这是由于染料在电磁光谱的这些区域中的电子激发而发生的。激发的光敏染料可促进电子转移至催化剂的导带,从而增强光催化作用。由此,由于在大范围的电磁波谱中对有用的光子进行了俘获以及这些复合材料的能量转换,利用太阳辐射进行废水处理变得很有趣。

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