首页> 外国专利> PROCESS FOR PRODUCING MIDDLE DISTILLATE FROM FISCHER-TROPSCH WAXES USING A CATALYST BASED ON A ZEOLITE MODIFIED BY A BASIC TREATMENT

PROCESS FOR PRODUCING MIDDLE DISTILLATE FROM FISCHER-TROPSCH WAXES USING A CATALYST BASED ON A ZEOLITE MODIFIED BY A BASIC TREATMENT

机译:使用基于基本处理改性的沸石的催化剂从费-托蜡生产中馏分的方法

摘要

The present invention describes a process for producing middle distillates from a paraffinic feedstock produced by Fischer-Tropsch synthesis, using a hydrocracking/hydroisomerization catalyst comprising at least one hydro-dehydrogenating metal chosen from the group formed by the metals from group VIB and from group VIII of the Periodic Table and a support comprising at least one dealuminated zeolite Y having an initial overall atomic ratio of silicon to aluminium of between 2.5 and 20, an initial extra-lattice aluminium atom weight fraction of greater than 10%, relative to the total weight of the aluminium present in the zeolite, an initial mesoporous volume measured by nitrogen porosimetry of greater than 0.07 ml.g-1, and an initial lattice parameter a0 of the unit cell between 24.38 Å and 24.30 Å, said zeolite being modified by a) a step of basic treatment consisting of mixing said dealuminated zeolite Y with a basic aqueous solution, and at least one step c) of heat treatment.
机译:本发明描述了一种使用加氢裂化/加氢异构化催化剂从由费-托合成法生产的链烷烃原料生产中间馏分的方法,所述加氢裂化/加氢异构化催化剂包含至少一种选自由VIB族金属和VIII族金属形成的组的加氢脱氢金属。元素周期表的组成和包含至少一种脱铝沸石Y的载体,所述沸石Y的初始硅与铝的总原子比为2.5至20,初始晶格外铝原子重量分数相对于总重量大于10%沸石中存在的铝的量,通过氮孔隙率法测得的初始中孔体积大于0.07 ml.g -1 和该单元的初始晶格参数a 0 在24.38至24.30之间的小室中,所述沸石通过以下步骤改性:a)基本处理步骤,包括将所述脱铝沸石Y与碱性水溶液混合,以及至少一个步骤c) 热处理。

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