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POLYMERIZABLE CHIRAL COMPOUNDS CONTAINING 2,6-NAPHTHYL- AND ISOMANNITE UNITS, AND USE THEREOF AS CHIRAL DOPANTS

机译:包含2,6-萘基和异甘露酸酯单元的可聚合手性化合物,并用作手性掺杂剂

摘要

The present invention relates to compounds of the general formula I in which the variables are each defined as follows: W is a (Y4-T2-)s(Y3-A2-)tY2-Z2 moiety, Z1, Z2 are each independently unreactive radicals as defined more specifically in the description or reactive radicals through which polymerization can be brought about, A1, A2 are each independently spacers as defined more specifically in the description, Y1 to Y5 are linking units as defined more specifically in the description, Y6 is a chemical single bond or -CO-, T1, T2 are each independently, as defined more specifically in the description, divalent saturated or unsaturated, optionally substituted and optionally fused iso- or heterocyclic radicals, Q is substituents as defined more specifically in the description, r, t are each independently 0 or 1, s is 0, 1, 2 or 3 and q is 0, 1, 2, 3 or 4. The invention further relates to a liquid-crystalline composition which comprises at least one compound of the formula I, and to the use of the compounds of the formula I as chiral dopants.
机译:本发明涉及通式I的化合物,其中各变量如下定义:W是(Y4-T2-)s(Y3-A2-)tY2-Z2部分,Z1,Z2各自独立地是不活泼的基团如在说明书中更具体定义的或可引起聚合的反应性自由基,A 1,A 2各自独立地是如在说明书中更具体定义的间隔基,Y 1至Y 5是如在说明书中更具体定义的连接单元,Y 6是化学单键或-CO-,T1,T2各自独立地(如说明书中更具体地定义)为二价饱和或不饱和,任选取代且任选稠合的异或杂环基,Q为如说明书中更具体定义的取代基, r,t分别独立地为0或1,s为0、1、2或3,q为0、1、2、3或4。本发明进一步涉及一种液晶组合物,其包含至少一种所述化合物。一级方程式式I化合物作为手性掺杂剂的用途。

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