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CARBONYL DERIVATIVES HAVING A C3 SYMMETRY, THEIR PREPARATION AND USES THEREOF

机译:具有C3对称性的羰基衍生物,其制备及其用途

摘要

The invention relates to 1,3,5-benzene derivatives and corresponding radical-anions and radical-cations of the general formula (I): wherein: Z is a group chosen from among C=O, CONH, CONR, CONAr; m is an integer 0, preferably m = 1; A is a group chosen from among the radicals of: biphenylene, carbazole, fluoranthene, fluorene, dibenzothiofene, dibenzofurane, fluorenone, bifluorenylidene, triphenylene, cyclooctatetraene (COT), dibenzocyclooctatetraene (DBCOT), coronene, acenaphtylene, triptycene, azulene, benzo(ghi)fluoranthene, 2-phenyl-l,3,4-oxadiazole, anthracene. R and Ar are alkyl and aryl respectively and have the meaning indicated herein below. The invention also relates to the method for synthesizing said compounds and to their use in particular as components of matrices in the molecular electronics, spintronics and telecom fields.
机译:本发明涉及通式(I)的1,3,5-苯衍生物和相应的自由基-阴离子和自由基-阳离子:其中:Z是选自C = O,CONH,CONR,CONAr的基团; m是> 0的整数,优选地m = 1; A是选自以下基团的基团:联苯撑,咔唑,荧蒽,芴,二苯并噻吩,二苯并呋喃,芴酮,联芴基,三苯撑,环辛烯(COT),二苯并环辛烯(DBCOT),co烯,a苯,三苯并戊烯,荧蒽,2-苯基-1,3,4-恶二唑,蒽。 R和Ar分别是烷基和芳基,并具有以下含义。本发明还涉及合成所述化合物的方法,尤其涉及它们在分子电子,自旋电子学和电信领域中作为基质组分的用途。

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