Potentiometric titration method and potentiometric titration apparatus

摘要

The present invention relates to a potentiometric titration method comprising assuming a titration curve and a differential curve from measured values; computing a straight line (D) connecting the two measured values on the titration curve which are present adjacent to a tentative equivalence point (P); computing a first estimation line (B1) and a second estimation line (B2) by a least squares method based on a set of the measured values (d1), (d2) and (d3) and a set of the measured values (d4), (d5) and (d6), respectively, on the titration curve, which are respectively spaced by a predetermined level apart from the tentative equivalence point (P) by using the number of decision points (n) as an index wherein the number of decision points (n) represents the number of measured values on the previously set titration curve; computing an intermediate line (C) between the first estimation line (B1) and the second estimation line (B2); and computing an intersection point (A) of the intermediate line (C) and the straight line (D) to read out a value of the intersection point on an abscissa axis as an equivalence point (a) of the titration.