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Novel Synthesis method of Pt/C catalyst, catalyst and PEMFC using the same

机译:Pt / C催化剂的新型合成方法,使用该催化剂的催化剂及peMFC

摘要

The present invention relates to a method for preparing a platinum / carbon catalyst, comprising: dissolving urea in water to prepare an aqueous urea solution, dispersing a carbon carrier in an aqueous urea solution, and injecting chloroplatinic acid to hydrolyze the urea. The hydroxy ions and the chloroplatinic acid are hydrated to react with ions of a specific chemical formula to synthesize chlorinated hydride platinum compounds, adsorbing on a carbon carrier, and injecting ethylene glycol to ethylene glycol. Reducing the platinum chloride chloride compound to the platinum particles, the particle size and distribution of the particle size is characterized in that it is determined by the amount of urea dissolved in the aqueous urea solution.;The platinum / carbon catalyst prepared by the production method of the present invention can maintain the particle size and particle size distribution of the platinum particles while increasing the amount of platinum supported thereon, and improve the dispersion degree of the platinum particles, thereby providing an electrochemical active area of the catalyst. It is possible to increase the activity of the catalyst significantly by increasing the power density of the proton exchange membrane fuel cell. In addition, since it is made of a simple process by a one-pot in an aqueous solution of a relatively low temperature, it is possible to reduce the production cost of the platinum / carbon catalyst, has the advantage of an environmentally friendly process.
机译:本发明涉及一种制备铂/碳催化剂的方法,该方法包括:将尿素溶解在水中以制备尿素水溶液;将碳载体分散在尿素水溶液中;以及注入氯铂酸以水解尿素。使羟基离子和氯铂酸水合以与特定化学式的离子反应,以合成氯化氢铂化合物,吸附在碳载体上,并将乙二醇注入乙二醇。将氯化铂氯化物还原成铂颗粒,其粒径和粒径分布的特征在于它是由溶解在尿素水溶液中的尿素的量决定的;通过该制备方法制备的铂/碳催化剂本发明的催化剂可以保持铂颗粒的粒度和粒度分布,同时增加负载在其上的铂的量,并改善铂颗粒的分散度,从而提供催化剂的电化学活性面积。通过增加质子交换膜燃料电池的功率密度,可以显着提高催化剂的活性。另外,由于通过一锅法在较低温度的水溶液中通过简单的方法制成,因此可以降低铂/碳催化剂的生产成本,具有环境友好的方法的优点。

著录项

  • 公开/公告号KR101077969B1

    专利类型

  • 公开/公告日2011-10-31

    原文格式PDF

  • 申请/专利权人

    申请/专利号KR20090073164

  • 发明设计人 유종성;

    申请日2009-08-10

  • 分类号B01J27/20;B01J23/42;H01M4/94;

  • 国家 KR

  • 入库时间 2022-08-21 17:49:33

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