, where Alkyl =Et, i-Pr, i-Bu, Bn, where C60-fullerene reacts with α-alkyldiazoacetic ether of general formula N2C(alkyl)COOEt, where alkyl = Et, i-Pr, i-Bu, Bn, in o-dichlorobenzene in the presence of a three-component catalyst {Pd(acac)2:2PPh3:4Et3Al}, taken in molar ratio C60-fullerene: α-alkyldiazoacetic ether: Pd(acac)2:PPh3:Et3Al=0.01:(0.05-0.15):(0.0015-0.0025):(0.003-0.005):(0.006-0.01), preferably 0.01:0.1:0.002:0.004:0.008, at temperature of 40°C for 0.25-1.0 hours. 1'-alkyl-1'-ethylformyl-(C60-1h)[5,6]fullero[2',3':1,9]cyclopropanes (1) and 1'a-alkyl-1'a ethylformyl-1'a-carba-1'(2')a-homo(C60-Ih)[5,6]fullerenes (2) are obtained in ratio of 1:1 and total output of 55-79%.;EFFECT: high yield.;1 tbl, 10 ex"/>
METHOD FOR COMBINED SYNTHESIS OF 1'-ALKYL-1'-ETHYLFORMYL-(C<Sub>60</Sub>-I<Sub>h</Sub>)5,6FULLERO2',3';1,9CYCLOPROPANES AND 1'a-ALKYL-1'a-ETHYLFORMYL-1'a-CARBA-1'(2')a-HOMO(C<Sub>60</Sub>-I<Sub>h</Sub>)5,6FULLERENES
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METHOD FOR COMBINED SYNTHESIS OF 1'-ALKYL-1'-ETHYLFORMYL-(C60-Ih)5,6FULLERO2',3';1,9CYCLOPROPANES AND 1'a-ALKYL-1'a-ETHYLFORMYL-1'a-CARBA-1'(2')a-HOMO(C60-Ih)5,6FULLERENES
METHOD FOR COMBINED SYNTHESIS OF 1'-ALKYL-1'-ETHYLFORMYL-(C60-Ih)5,6FULLERO2',3';1,9CYCLOPROPANES AND 1'a-ALKYL-1'a-ETHYLFORMYL-1'a-CARBA-1'(2')a-HOMO(C60-Ih)5,6FULLERENES
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机译：1'-烷基-1'-乙基甲酰基-（C 60 -I h ）[5,6]富勒罗[2'，3'; 1]的合成方法，9]环丙烷和1'a-烷基-1'a-乙基甲酰基-1'a-CARBA-1'（2'）a-HOMO（C 60 -I h ）[5,6]富勒烯
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FIELD: chemistry.;SUBSTANCE: method involves combined synthesis of 1'-alkyl-1'-ethylformyl-(C60-Ih)[5,6]fullero[2':,3':1,9]cyclopropanes and 1'a-alkyl-1'a ethylformyl-1'a-carba-1'(2')a-homo(C60-Ih)[5,6]fullerenes of general formula ; , where Alkyl =Et, i-Pr, i-Bu, Bn, where C60-fullerene reacts with α-alkyldiazoacetic ether of general formula N2C(alkyl)COOEt, where alkyl = Et, i-Pr, i-Bu, Bn, in o-dichlorobenzene in the presence of a three-component catalyst {Pd(acac)2:2PPh3:4Et3Al}, taken in molar ratio C60-fullerene: α-alkyldiazoacetic ether: Pd(acac)2:PPh3:Et3Al=0.01:(0.05-0.15):(0.0015-0.0025):(0.003-0.005):(0.006-0.01), preferably 0.01:0.1:0.002:0.004:0.008, at temperature of 40°C for 0.25-1.0 hours. 1'-alkyl-1'-ethylformyl-(C60-1h)[5,6]fullero[2',3':1,9]cyclopropanes (1) and 1'a-alkyl-1'a ethylformyl-1'a-carba-1'(2')a-homo(C60-Ih)[5,6]fullerenes (2) are obtained in ratio of 1:1 and total output of 55-79%.;EFFECT: high yield.;1 tbl, 10 ex
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机译：领域：化学。;实质：方法涉及1'-烷基-1'-乙基甲酰基-（C 60 -I h ）[5,6] fullero的组合合成[ 2'：，3'：1,9]环丙烷和1'a-烷基-1'a乙基甲酰基-1'a-carba-1'（2'）a-高纯（C 60 - I h ）[5,6]通式的富勒烯; ，其中Alkyl = Et，i-Pr，i-Bu，Bn，其中C < Sub> 60 -富勒烯与通式N 2 C（烷基）COOEt的α-烷基重氮乙酸醚反应，其中烷基= Et，i-Pr，i-Bu，Bn，在o中三组分催化剂{Pd（acac） 2 ：2PPh 3 ：4Et 3 Al}存在下的二氯苯比率C 60 -富勒烯：α-烷基重氮乙酸醚：Pd（acac） 2 ：PPh 3 ：Et 3 Al = 0.01：（0.05-0.15）:( 0.0015-0.0025）:( 0.003-0.005）:( 0.006-0.01），优选0.01：0.1：0.002：0.004：0.008，在40°C的温度下0.25-1.0小时。 1'-烷基-1'-乙基甲酰基-（C 60 -1 h ）[5,6] fullero [2'，3'：1,9]环丙烷（ 1）和1'a-烷基-1'a乙基甲酰基-1'a-carba-1'（2'）a-homo（C 60 -I h ） [5,6]富勒烯（2）的比例为1：1，总产量为55-79％。效果：高收率; 1 tbl，10 ex
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