Production manner and those uses of the jiarukiruhosuhuin Acid, - ester and the - salt which use alkyl alcohol/acrolein

摘要

As for this invention, being production manner of the monokarubokishi functional conversion jiarukiruhosuhuin Acid, - ester and the - salt,a) Reacting phosphine acid source (i), with olefin (iv) under existing of catalytic converter A, the alkyl sub- phosphon Acid, it makes that salt or ester (ii),b) In this way, the alkyl sub- phosphon Acid which it occurs, formula (v) and/or (reacting that salt or ester (ii), with VI') chemical compound under existing of catalytic converter, B monofunctional conversion jiarukiruhosuhuin Acid derivative (vi) and/or (VI') with to do, andc) In this way, monofunctional conversion jiarukiruhosuhuin Acid derivative (vi) it can and/or (reacting under existing of VI') catalytic converter C, the next formula Conversion 1 To make monokarubokishi functional conversion jiarukiruhosuhuin Acid derivative (iii), in this case, R, R, R, R, R, R and R to differ, become independent equality or mutually, H, C C alkyl and C C aryl, the C C aralkyl, to mean C C alkyl aryl even among them, and X and Y to differ equality or, and becoming independent mutually, H, C C alkyl and C C aryl, the C C aralkyl, C C alkyl aryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr and MnCu, Ni, Li, Na and K and/or to proton the nitrogen base which is converted is displayed, and catalytic converter A and C, the succession metal, and/or succession metal chemical compound, and/or the succession metal and/or succession metal chemical compound are the catalytic converter system which is formed at least from one ligand, and catalytic converter B, peroxide formation chemical compound, and/or per oxo compound, and/or azo chemical compound, and/or alkali - and/or the alkaline earths metal, the - hydride and/or is - alcoholate, it regards aforementioned manner.