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Fluorine-containing adamantane derivatives, resin composition containing the same polymerizable group and the fluorine-containing adamantane derivatives
Fluorine-containing adamantane derivatives, resin composition containing the same polymerizable group and the fluorine-containing adamantane derivatives
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机译:含氟金刚烷衍生物,含有相同聚合基团的树脂组合物和含氟金刚烷衍生物
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摘要
Provided are a polymerizable group-containing and fluorine-containing adamantane derivative capable of affording a cured product having good heat resistance, good mechanical properties such as surface hardness and a low refractive index, a resin composition containing such a polymerizable group-containing adamantane derivative, and a fluorine-containing adamantane derivative which is useful as a reaction intermediate used for the production of the polymerizable group-containing and fluorine-containing adamantane derivative. Specifically provided are a fluorine-containing adamantane derivative represented by the general formula (I) below, a polymerizable group-containing and fluorine-containing adamantane derivative represented by the general formula (II) below, and a resin composition containing such a polymerizable group-containing and fluorine-containing adamantane derivative. In the formulas, X 1 and X 2 each represent OH or NH 2 , a, b and c each represent an integer of 0 or more and a + b + c ‰¥ 1, for example a = b = 0 and c = 1, Z 3 represents, for example, -C 2 H 4 -, s and t each represent an integer of 1 to 15, u represents an integer of 0 to 14, s + t + u = 16, for example s = 2, t = 14, u = 0, and X 3 represents, for example, -O-CO-CH=CH 2 .
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机译:提供一种能够提供具有良好的耐热性,良好的机械性能如表面硬度和低折射率的固化产物的含可聚合基团和含氟的金刚烷衍生物,包含这种含可聚合基团的金刚烷衍生物的树脂组合物,以及含氟金刚烷衍生物,其用作用于生产含聚合基团和含氟金刚烷衍生物的反应中间体。具体提供以下通式(I)表示的含氟金刚烷衍生物,下述通式(II)表示的含聚合性基团和含氟的金刚烷衍生物以及含有这样的聚合性基团的树脂组合物。含和含氟的金刚烷衍生物。式中,X 1和X 2分别表示OH或NH 2,a,b和c分别表示0以上的整数,并且a + b + c≥1,例如a = b = 0和c = 1 ,Z 3表示例如-C 2 H 4-,s和t各自表示1到15的整数,u表示0到14的整数,s + t + u = 16,例如s = 2 t = 14,u = 0,并且X 3表示例如-O-CO-CH = CH 2。
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