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Optical active die tris - (2,3 epoxy propyl) - isocyanurate and high melting point die tris - (2,3 epoxy propyl) - isocyanurate

机译:光学活性模具tris-(2,3环氧丙基)-异氰脲酸酯和高熔点模具tris-(2,3环氧丙基)-异氰脲酸酯

摘要

PROBLEM TO BE SOLVED: To obtain the subject new compounds useful as an optical resolving agent, a polymeric catalyst, a material such as a nonlinear optical material, a compound reactive with epoxy groups or a cross-linking agent for a reactive polymer. ;SOLUTION: This compound is (2R,2'R,2"R)-tris-(2,3-epoxypropyl) isocyanurate. The compound is obtained by reacting one mol of isocyanuric acid with 3-60 mol of an optically active epihalohydrin by using at least one kind of compound selected from the group consisting of a tertiary amine, a quaternary ammonium salt, a tri-substituted phosphine and a quaternary phosphonium salt to produce a 2-hydroxy-3-halopropyl isocyanurate. The optically active epihalohydrin used in an excessive amount is then recovered by a distilling off method and a solvent is subsequently added to dilute the 2-hydroxy-3-halopropy isocyanurate. An alkali metal hydroxide or an alkali metal alcoholate is added afford the (2R,2'R,2"R)-tris-(2,3-epoxypropyl) isocyanurate. The amount of water in the reactional mixture is preferably regulated to 1% when carrying out the reaction.;COPYRIGHT: (C)1999,JPO
机译:要解决的问题:为了获得主题的新化合物,它们可用作旋光拆分剂,聚合物催化剂,诸如非线性光学材料之类的材料,可与环氧基反应的化合物或用于反应性聚合物的交联剂。 ;解决方案:该化合物为(2R,2'R,2“ R)-三-(2,3-环氧丙基)异氰脲酸酯。该化合物是通过使一摩尔异氰尿酸与3-60摩尔光学活性表卤代醇反应制得的通过使用选自叔胺,季铵盐,三取代的膦和季phospho盐中的至少一种化合物来制备2-羟基-3-卤代丙基异氰脲酸酯。然后通过蒸馏方法回收过量的二恶英,然后添加溶剂以稀释2-羟基-3-卤代丙异氰脲酸酯。添加碱金属氢氧化物或碱金属醇盐,得到(2R,2'R, 2″ R)-三-(2,3-环氧丙基)异氰脲酸酯。反应进行时,优选将反应混合物中的水量调节至<1%。COPYRIGHT:(C)1999,JPO

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