Method for electrochemically detecting different oxidant and halide anion species in a sample. According to one embodiment, the method uses a sensor including a boron-doped diamond working electrode, a platinum mesh counter electrode, a silver/silver chloride reference electrode, a potentiostat coupled to the three electrodes, and a computer coupled to the potentiostat. The sensor measures current resulting from differential pulse non-stripping voltammetry, thereby enabling different oxidants and halide anions from a plurality of such species to be detected by distinct responses. Peaks in the current signal result at characteristic voltages when a species is oxidized to a higher oxidation state, and the concentration of a particular species is determined by the magnitude of the current peak. The sensor response time is rapid and shows high sensitivity and selectivity for oxidants and halide anions. The sensor may be a hand-held or in-line device and may be used in a feedback-control system.
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