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Silyl (meth)acrylate compound containing a siloxy group having a bulky substituent and its production method
Silyl (meth)acrylate compound containing a siloxy group having a bulky substituent and its production method
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机译:含有具有大取代基的甲硅烷氧基的(甲基)丙烯酸甲硅烷基酯化合物及其生产方法
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摘要
A silyl (meth)acrylate compound containing a siloxy group having a bulky substituent is provided. The compound is represented by the following general formula (1):; wherein R1 and R2 are independently a C3-10 monovalent branched hydrocarbon group having a hydrocarbon group at α or β position or a monovalent C3-10 cyclic hydrocarbon group; R3, R4, and R5 are independently an unsubstituted or substituted C1-20 hydrocarbon group or a siloxy group represented by the following general formula (2):—OSiR7R8R9 (2)wherein R7, R8, and R9 are independently an unsubstituted or substituted C1-20 hydrocarbon group; and R6 is hydrogen atom or methyl group. This compound is hydrolyzed at a reduced speed, and use of a polymer obtained by copolymerization with an alkyl methacrylate is capable of suppressing attachment of marine organisms to the ship with no or reduced biocide, and this polymer is useful for a hydrolytic self-polishing paint.
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机译:提供含有具有大取代基的甲硅烷氧基的(甲基)丙烯酸甲硅烷基化合物。该化合物由以下通式(1)表示: 化学>其中R 1 Sup>和R 2 Sup>独立地是在α或β位置具有烃基的C 3-10 Sub>单价支链烃基或一价C 3-10 Sub>环烃基; R 3 Sup>,R 4 Sup>和R 5 Sup>独立地是未取代或取代的C 1-20 Sub>烃基或由以下通式(2)表示的甲硅烷氧基:<?in-line-formulae description =“在线公式” end =“ lead”?>-OSiR 7 Sup> R 8 Sup> R 9 Sup> (2)<?in-line-formulae description =“在线公式” end =“ tail”?>其中R 7 Sup>,R 8 Sup>和R 9 Sup>独立地是未取代或取代的C 1-20 Sub>烃基;和R 6 Sup>是氢原子或甲基。该化合物以降低的速度水解,并且通过与甲基丙烯酸烷基酯共聚获得的聚合物的使用能够抑制海洋生物附着到船上而没有或没有杀生物剂,该聚合物可用于水解自抛光漆。
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