首页> 外国专利> PROCESS FOR THE PREPARATION OF AN ADDITIVE COMPOSITION, HIGHLY GRAFTED MULTIFUNCTIONAL OLEFIN COPOLYMER PREPARED BY SAID PROCESS AND LUBRICANT OIL COMPRISING SAID COPOLYMER

PROCESS FOR THE PREPARATION OF AN ADDITIVE COMPOSITION, HIGHLY GRAFTED MULTIFUNCTIONAL OLEFIN COPOLYMER PREPARED BY SAID PROCESS AND LUBRICANT OIL COMPRISING SAID COPOLYMER

机译:由所述方法和包含所述共聚物的润滑油制备的添加剂组合物,高度接枝的多功能烯烃共聚物的制备方法

摘要

The invention relates to a process for an additive composition comprising an amidized or imidized polymer. The invention further relates to a highly grafted, multi-functional lubricant additive useful to improve the viscosity index and dispersancy properties of a lubricating oil composition. The present invention also relates to a method of extending lubricant drain intervals and improving fuel economy and fuel economy durability. The additive composition is prepared by: (A) reacting an olefin copolymer of ethylene and at least one C3 to C23 α-olefin comprising from about 15 to 80 mole percent of ethylene, from about 20 to 85 mole percent of said C3 to C23 α-olefin and from about 0 to 15 wt percent of a polyene, said copolymer having a number average molecular weight ranging from 1,000 to 500,000, with an olefinic carboxylic acid acylating agent, said process comprising heating said polymer to a molten condition at a temperature in the range of 60°C to 240°C, grafting, in a first extruder or a first mixing device, said olefinic carboxylic acylating agent onto said copolymer, optionally subsequently reducing the molecular weight of said copolymer at a temperature in the range of 250°C to 350°C, thereby producing a grafted, reduced molecular weight acylated copolymer having a number average molecular weight ranging from 1,000 to 80,000 and having at least 0.2 - 20 molecules of said carboxylic acid acylating agent grafted per 1000 C atoms of said olefin copolymer, and (B) reacting, in a second extruder or a second mixing device, said acylated copolymer made in (A) with a polyamine.
机译:本发明涉及一种包含酰胺化或酰亚胺化聚合物的添加剂组合物的方法。本发明进一步涉及高度接枝的多功能润滑剂添加剂,其可用于改善润滑油组合物的粘度指数和分散性。本发明还涉及一种延长润滑剂排放间隔并改善燃料经济性和燃料经济性耐久性的方法。所述添加剂组合物通过以下方法制备:(A)使乙烯与至少一种包含约15-80摩尔%的乙烯,约20-85摩尔%的所述C3-C23α的C 3 -C 23α-烯烃的烯烃共聚物反应。 -烯烃和约0-15%(重量)的多烯,所述共聚物的数均分子量为1,000-500,000,并带有烯烃羧酸酰化剂,所述方法包括将所述聚合物在200℃的温度下加热至熔融状态。在第一挤出机或第一混合装置中,将所述烯烃羧酸酰化剂接枝到所述共聚物上,在60℃至240℃的温度范围内接枝,任选随后在250℃的温度范围内降低所述共聚物的分子量℃至350℃,从而制得数均分子量为1,000至80,000且具有至少0.2至20个所述羧酸酰化剂分子的接枝的,分子量降低的酰化共聚物。所述烯烃共聚物的每1000个C原子接枝,并且(B)在第二挤出机或第二混合装置中使(A)中制备的所述酰化共聚物与多胺反应。

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