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Preparation of molecularly imprinted polymers soluble and colloidal by living polymerization.

机译:通过活性聚合制备可溶和胶体的分子印迹聚合物。

摘要

Process for the preparation of a solution or colloidal suspension of a polymer having (i) a synthesis step comprising living polymerization template-directed functional monomers performed in the presence of a template, thereby producing a complementary polymer in that at least a part is complementary to at least part of the template, and including the step of terminating the living polymerization are formed when suitable for the preparation of the solution or colloidal suspension complementary polymer particles; and (ii) a separation step comprising providing a chromatographic medium with the immobilized template and carry with it an affinity chromatography of the product of synthetic step to isolate a fraction of complementary polymers having a specific affinity for the template.
机译:具有(i)合成步骤的聚合物溶液或胶体悬浮液的制备方法,该合成步骤包括在模板的存在下进行的,以活性聚合为模板的官能单体,从而制备互补聚合物,其中至少一部分与当适于制备溶液或胶体悬浮液互补聚合物颗粒时,形成至少部分模板,并包括终止活性聚合的步骤。 (ii)分离步骤,包括为色谱介质提供固定的模板,并对其进行合成步骤产物的亲和色谱,以分离对模板具有特定亲和力的一部分互补聚合物。

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