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GAS DIFFUSION ELECTRODE, DEVICE AND PROCESS FOR THE PRODUCTION OF HYDROGEN PEROXIDE

机译:气体扩散电极,装置和过氧化氢的生产过程

摘要

The invention relates to a device for producing hydrogen peroxide comprising a two-compartment electrochemical cell which comprises an anode, a cathode and an aqueous electrolyte, said compartments being separated by an ion exchange membrane, said cathode being an electrode with gaseous diffusion, said device being characterized in that said cathode comprises at least one catalyst based on Co, N and C made from at least one precursor comprising cobalt and not containing nitrogen such as cobalt, or a catalyst comprising a derivative of 5,10,15,20 tetrakis (4-methoxyphenyl) 21H, 23H Porphyrin Cobalt II (or CoTMPP), such as its initial content of CoTMPP, in weight of cobalt on carbon, is less than or equal to 0.5%, preferably 0.2%. Method of implementing such a device Gas diffusion electrode comprising such a catalyst.
机译:用于生产过氧化氢的装置技术领域本发明涉及一种用于生产过氧化氢的装置,该装置包括由阳极,阴极和水性电解质组成的两室式电化学电池,所述室由离子交换膜隔开,所述阴极是具有气体扩散的电极。其特征在于,所述阴极包括至少一种基于Co,N和C的催化剂,该催化剂由至少一种包含钴但不包含氮的前体(例如钴)制成,或包含5、10、15、20四元衍生物的催化剂( (4-甲氧基苯基)21H,23H卟啉钴II(或CoTMPP),例如其CoTMPP的初始含量(以钴碳重量计)小于或等于0.5%,优选为0.2%。实现这种装置的方法,包括这种催化剂的气体扩散电极。

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