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HYBRID NANOCOMPOSITE FOR AQUATIC MEDIA REMEDIATION AND RESPECTIVE PRODUCTION METHOD

机译:混合纳米复合材料在水生介质修复及生产中的应用

摘要

The present invention relates to a polymeric hybrid nanocomposite composed of inorganic nanoparticles dispersed in an organic matrix, for remediation of aquatic media contaminated by anions, such as phosphates, nitrates, sulphates and polyphosphates. The nanocomposite is based on polypropylene grafted with maleic anhydride and aluminium isopropoxide and creates strong (covalent or ionic) chemical bonds between the organic and inorganic components, imparting high mechanical strength associated with indissolubility of the components in the body of water. The hybrid nanocomposite can be applied in situ, in which case the material is used to prepare a permeable reactive barrier to be introduced into the aquatic medium, and through which the water to be treated flows; or ex situ, in which case the water to be treated is pumped, is made to pass through a filter that contains the hybrid nanocomposite and is then returned to the aquatic medium. The hybrid nanocomposite can be moulded according to the type of use and application site. Several characterization techniques, such as spectroscopic methods and analysis of rheological properties, zero point charge and kinetics of phosphate ion removal, demonstrate that the product does not change the pH of or contaminates the aquatic medium.
机译:本发明涉及由分散在有机基质中的无机纳米颗粒组成的聚合物杂化纳米复合材料,用于补救被阴离子污染的水生介质,例如磷酸盐,硝酸盐,硫酸盐和多磷酸盐。纳米复合材料基于接枝有马来酸酐和异丙醇铝的聚丙烯,并在有机和无机组分之间产生强(共价或离子)化学键,从而赋予了高机械强度,这些机械强度与组分在水体中的不溶性有关。杂化纳米复合材料可以原位施用,在这种情况下,该材料用于制备可渗透的反应性屏障,将其引入水生介质中,待处理的水流过该屏障。或异地(在这种情况下,将要处理的水泵送)通过包含杂化纳米复合材料的过滤器,然后返回到水生介质中。杂化纳米复合材料可以根据使用类型和应用部位进行模塑。几种表征技术,例如分光光度法和流变学特性,零点电荷和磷酸根离子去除动力学的分析,证明该产品不会改变水介质的pH值或污染水介质。

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