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PHOTOSTABILIZATION OF RESVERATROL WITH ALKOXYCRYLENE COMPOUNDS

机译:烷炔化合物对白藜芦醇的光稳定作用

摘要

The photostabilizing electronic excited state energy - particularly singlet state energy from resveratrol compounds - has been found to be readily transferred to (accepted by) α- cyanodiphenylacrylate compounds having an alkoxy radical in the four (para) position (hereinafter "alkoxycrylenes") on one of the phenyl rings having the formula (I): wherein one of R1 and R2 is a straight or branched chain C1-C30 alkoxy radical, preferably C1-C8, more preferably methoxy, and the non-alkoxy radical R1 or R2 is hydrogen; and R3 is a straight or branched chain C1-C30 alkyl radical, preferably C2-C20. The alkoxycrylene compounds of formula (I) significantly increase the photostability of resveratrol compounds in a composition by at least 3-fold and as much as 10-fold or greater. The ability of the alkoxycrylene compounds to stabilize the resveratrol compound is concentration dependent, with the amount of resveratrol photostabilization increasing with the concentration of the alkoxycrylene compound.
机译:已发现光稳定化的电子激发态能量-特别是白藜芦醇化合物的单态能量->容易转移到(被(接受)具有四个(对位)烷氧基的α-氰基二苯基丙烯酸酯化合物(在以下具有式(I)的苯环之一上:式中,R 1 和R 2 之一是直链或支链C 1 -C 30 烷氧基,优选C 1 -C 8 ,更优选甲氧基,和非烷氧基R 1 或R 2 是氢;并且R 3 是直链或支链C 1 -C 30 烷基,优选C 2 -C 20 。式(I)的烷氧基​​丙烯化合物将白藜芦醇化合物在组合物中的光稳定性显着提高至少3倍并且高达10倍或更大。烷氧基丙烯化合物稳定白藜芦醇化合物的能力取决于浓度,其中白藜芦醇光稳定化的量随烷氧基丙烯化合物的浓度而增加。

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