首页> 外国专利> PALLADIUM CATALYST SUPPORTED ON ALUMINA XEROGEL SUPPORT WITH CONTROLLED ACIDITY AND PRODUCTION METHOD OF -BUTYROLACTONE BY HYDROGENATION OF SUCCINIC ACID USING SAID CATALYST

PALLADIUM CATALYST SUPPORTED ON ALUMINA XEROGEL SUPPORT WITH CONTROLLED ACIDITY AND PRODUCTION METHOD OF -BUTYROLACTONE BY HYDROGENATION OF SUCCINIC ACID USING SAID CATALYST

机译:酸控制铝载体上负载的钯催化剂及丁二酸加氢制丁酸内酯的制备方法

摘要

PURPOSE: A palladium catalyst supported on an alumina xerogel support with controlled acidity and a method for preparing -butyrolactone based on the hydrogenation of succinic acid using the catalyst are provided to thermo-chemically stabilize a catalytic process by optimally combining the acid characteristic of the support and the hydrogenation activity of palladium. CONSTITUTION: A palladium catalyst supported on an alumina xerogel support with controlled acidity is obtained by gelating an aluminum precursor based on a sol-gel method and implementing a thermal treatment. The average pore size of the palladium catalyst is between 2 and 10nm. The surface area of the palladium catalyst is between 100 and 300m^2/g. The temperature of the thermal treatment is between 700 and 900 degrees Celsius. 1-10 parts by weight of the palladium catalyst is supported by 100 parts by weight of the alumina xerogel support.
机译:目的:提供一种在酸性控制下的氧化铝干凝胶载体上负载的钯催化剂和一种基于琥珀酸加氢制备丁酸内酯的方法,该催化剂可通过优化结合载体的酸性质来热化学稳定催化过程和钯的氢化活性。组成:负载在氧化铝干凝胶载体上的酸度受控的钯催化剂是通过基于溶胶-凝胶法将铝前体胶凝并进行热处理而制得的。钯催化剂的平均孔径在2至10nm之间。钯催化剂的表面积在100和300m 2 / g之间。热处理的温度在700到900摄氏度之间。 1-10重量份的钯催化剂由100重量份的氧化铝干凝胶载体负载。

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