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SENSOR CONTAINING FLUORESCEIN-BASED COMPOUND OF PERBORATE SELECTIVITY AND A METHOD FOR DETECTING PERBORATE USING THE SAME CAPABLE OF VISIBLY DETECTING THE PERBORATE THROUGH AN OXIDIZING REACTION
SENSOR CONTAINING FLUORESCEIN-BASED COMPOUND OF PERBORATE SELECTIVITY AND A METHOD FOR DETECTING PERBORATE USING THE SAME CAPABLE OF VISIBLY DETECTING THE PERBORATE THROUGH AN OXIDIZING REACTION
PURPOSE: A sensor containing fluorescein-based compound of perborate selectivity and a method for detecting perborate using the same are provided to rapidly detect the perborate and to use the fluorescein-based compound as a selective fluorescent sensor for the perborate.;CONSTITUTION: A sensor for perborate includes a compound represented by chemical formula 1. In the chemical formula 1, the R1 to R3 are respectively hydrogen, halogen, hydroxyl, cyano, carboxyl, or C1 to C6 alkyl group. The R4 represents hydrogen, bezothiazole, or benzo imidazole. The R5 represents carbonyl group. The R4 and the R5 forms a ring or a fused ring containing the X and the Z. The R6 to R8 are respectively hydrogen or halogen atoms. The Z represents a nitrogen atom or CR9 and represents a spiro atom to form a ring and a spiro compound containing the X and the Z. The R9 represents hydrogen, halogen, hydroxyl, cyano, or carboxyl group. The R10 and R11 are respectively hydrogen, halogen, or carboxyl functional group. The 12 and the R13 are respectively hydrogen or halogen. The X represents oxygen atom or sulfur atom.;COPYRIGHT KIPO 2012
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机译:目的:提供一种传感器,该传感器包含具有过硼酸盐选择性的荧光素基化合物,以及使用该传感器检测过硼酸盐的方法,以快速检测过硼酸盐,并将该荧光素基化合物用作过硼酸盐的选择性荧光传感器。用于过硼酸盐的化合物包括由化学式1表示的化合物。在化学式1中,R 1至R 3分别为氢,卤素,羟基,氰基,羧基或C 1至C 6烷基。 R 4代表氢,苯并噻唑或苯并咪唑。 R 5代表羰基。 R 4和R 5形成含有X和Z的环或稠环。R6至R 8分别是氢或卤素原子。 Z代表氮原子或CR9,代表形成环的螺原子和含有X和Z的螺化合物。R9代表氢,卤素,羟基,氰基或羧基。 R10和R11分别是氢,卤素或羧基官能团。 12和R13分别是氢或卤素。 X代表氧原子或硫原子。; COPYRIGHT KIPO 2012
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