首页> 外国专利> METHOD OF HYDROCONVERSION IN THE STATIONARY LAYER OF RAW OIL AFTER SELECTION OF EASY FRACTIONS OR WITHOUT SELECTION BY USING INTERCHANGEABLE REACTORS FOR THE PREPARATION OF PRE-CLEANED SINUMET

METHOD OF HYDROCONVERSION IN THE STATIONARY LAYER OF RAW OIL AFTER SELECTION OF EASY FRACTIONS OR WITHOUT SELECTION BY USING INTERCHANGEABLE REACTORS FOR THE PREPARATION OF PRE-CLEANED SINUMET

机译:选择简单的馏分后或不使用可互换的反应器进行选择以制备预先清洁的小茴香的原始油的稳态层中的加氢转化方法

摘要

1. The method of pre-treatment and hydroconversion in a stationary layer of hydrocarbon raw materials in the form of heavy crude oil containing at least 0.5 wt.% Asphaltenes and more than 10 wt.h / million metals (nickel and / or vanadium), to obtain a pre-refined synthetic crude oil, in which:! - hydrodemetallization of the feedstock is carried out in the hydrodemetallization section (HDM) containing at least 2 interchangeable reaction zones, each of which contains at least one hydrodemetallization catalyst; ! - then hydrocracking of at least a portion of at least partially demetallized effluent is carried out in a hydrocracking section (ICC) containing at least one hydrocracking catalyst in a stationary layer,! - then carry out hydrodesulfurization of at least part of the at least partially hydrocracked effluent in the hydrodesulfurization section containing at least one hydrodesulfurization catalyst! and in which the HDM and HDS sections operate in the presence of a catalyst system that contains at least two catalysts, one for HDM and the other for HDS, wherein the NSC step is performed between the HDM and HDS steps, wherein said HDM and HDS catalysts comprise at least one carrier consisting of a porous refractory oxide, at least one metal from group VIB and at least two metals from group VIII, one of which is the main promoter called VIII-1, and the other or others called co-promoter VIII-i / where i is from 2 d about 5, in these catalysts, elements of group VIII are present in amounts determined by the atomic ratio [VIII-1 / (VIII-1 + ... + VIII-i)],
机译:1.在烃原料的固定层中以重原油形式进行预处理和加氢转化的方法,所述重质原油包含至少0.5重量%的沥青质和超过10重量%/百万的金属(镍和/或钒) ,以获得预精制的合成原油,其中: -原料的加氢脱金属在加氢脱金属段(HDM)中进行,该加氢脱金属段包含至少两个可互换的反应区,每个反应区均包含至少一种加氢脱金属催化剂; ! -然后在包含至少一种加氢裂化催化剂的固定层中的加氢裂化段(ICC)中进行至少一部分至少部分脱金属的流出物的加氢裂化! -然后在含有至少一种加氢脱硫催化剂的加氢脱硫段中对至少部分至少部分加氢裂化的废水进行至少一部分的加氢脱硫!并且其中HDM和HDS部分在包含至少两种催化剂的催化剂体系的存在下操作,一种用于HDM,另一种用于HDS,其中NSC步骤在HDM和HDS步骤之间进行,其中所述HDM和HDS催化剂包含至少一种由多孔耐火氧化物,至少一种VIB族金属和至少两种VIII族金属组成的载体,其中一种是主助催化剂VIII-1,另一种或其他助催化剂VIII-i /,其中i为2 d约5,在这些催化剂中,VIII族元素的存在量由原子比[VIII-1 /(VIII-1 + ... + VIII-i)]确定,

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