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METHOD OF PRODUCING PHOTOCATALYTIC NANOCOMPOSITE CONTAINING TITANIUM DIOXIDE

机译:包含二氧化钛的光催化纳米复合材料的制备方法

摘要

FIELD: chemistry.;SUBSTANCE: invention can be used for photocatalytic treatment of water and air from organic compounds and pathogenic flora, with photocatalytic decomposition of water. In order to obtain a photocatalytic nanocomposite containing titanium dioxide, a transition metal salt is added in amount of 1.5-60 wt % in terms of metal to a titanium (IV) salt solution with concentration of 1.0-2.5 mol/l TiO2 while stirring and the salts undergo hydrolysis in ammonium hydroxide solution at 15-25°C for 0.1-0.25 hours with formation of a precipitate. The obtained precipitate is settled for 1.5-2.0 hours, separated, washed and thermally processed at 80-800°C for 0.5-1.0 hours. The titanium (IV) salt used is a chloride or sulphate, the iron (III) salt used is a chloride, sulphate or nitrate, the niobium (V) salt used is a fluoride and the tungsten (VI) salt used is sodium tungstate.;EFFECT: invention enables to increase photocatalytic activity of the titanium dioxide-based nanocomposite in the visible light region, lowers hydrolysis temperature and shortens duration of the method.;9 cl, 1 tbl
机译:领域:化学。物质:本发明可用于光催化分解有机化合物和致病菌群中的水和空气。为了获得包含二氧化钛的光催化纳米复合材料,将过渡金属盐以金属计以金属的1.5-60wt%的量添加到浓度为1.0-2.5mol / l的钛(IV)盐溶液中。 2 在搅拌下进行,盐在氢氧化铵溶液中于15-25°C水解0.1-0.25小时,形成沉淀。将获得的沉淀物沉降1.5-2.0小时,分离,洗涤并在80-800℃下热处理0.5-1.0小时。所用的钛(IV)盐是氯化物或硫酸盐,所用的铁(III)盐是氯化物,硫酸盐或硝酸盐,所用的铌(V)盐是氟化物,所用的钨(VI)盐是钨酸钠。效果:本发明能够提高可见光区域中二氧化钛基纳米复合材料的光催化活性,降低水解温度并缩短该方法的持续时间。9cl,1 tbl

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