首页> 外国专利> NON-FORMALDEHYDE CONTAINING EMULSION POLYMER DISPERSED COMPOSITION, CONTAINING COMPLETELY HYDROLYSED POLYVINYL ALCOHOL, USED AS COLLOIDAL STABILISER FOR ENHANCING THERMAL STABILITY

NON-FORMALDEHYDE CONTAINING EMULSION POLYMER DISPERSED COMPOSITION, CONTAINING COMPLETELY HYDROLYSED POLYVINYL ALCOHOL, USED AS COLLOIDAL STABILISER FOR ENHANCING THERMAL STABILITY

机译:包含乳液聚合的非甲醛聚合物分散体,包含完全水解的聚乙烯醇,用作提高热稳定性的胶体稳定剂

摘要

FIELD: chemistry.;SUBSTANCE: disclosed is use of (meth)acrylic acid amide(s) as a comonomer (comonomers) (b), meant for enhancing thermal stability using non-formaldehyde containing aqueous dispersion of a polymer obtained via emulsion copolymerisation of at least the following components: (a) vinyl ester monomer (monomers) and (b) a comonomer (comonomers) containing said amide derivatives of acrylic and/or methacrylic acid, in the presence of at least (c) a completely hydrolysed polyvinyl alcohol (PVOH), the average degree of hydrolysis of which is more than 95.00 mol %, wherein polymerisation does not include comonomers which are amide derivatives of N-alkylol(meth)acrylic acid, and thermal stability of the adhesive compound which is measured in form of a WATT 91 value in accordance with DIN EN 14257 is higher than that of samples obtained without using amide derivatives (b) of acrylic and/or methacrylic acid. The invention also discloses a non-formaldehyde containing polymer dispersion and a method of preparing said dispersion using (meth)acrylic acid amides, as well as a binder composition containing said aqueous polymer dispersion.;EFFECT: possibility of obtaining water resistant and heat resistant wood glue which does not decolour wood when gluing.;44 cl, 8 tbl, 40 ex
机译:领域:公开了(甲基)丙烯酸酰胺作为共聚单体(共聚单体)的用途(b),意在使用通过乳液共聚获得的聚合物的不含甲醛的水性分散体来提高热稳定性。至少以下组分:(a)乙烯基酯单体(单体)和(b)在至少(c)完全水解的聚乙烯醇的存在下,包含所述丙烯酸和/或甲基丙烯酸的酰胺衍生物的共聚单体(共聚单体)。 (PVOH),其平均水解度大于95.00 mol%,其中聚合不包括作为N-羟甲基(甲基)丙烯酸酰胺衍生物的共聚单体,以及以形式测量的粘合剂化合物的热稳定性根据DIN EN 14257的WATT 91值的平均值大于未使用丙烯酸和/或甲基丙烯酸的酰胺衍生物(b)获得的样品的值。本发明还公开了一种不含甲醛的聚合物分散体和使用(甲基)丙烯酸酰胺制备所述分散体的方法,以及包含所述水性聚合物分散体的粘合剂组合物。效果:获得耐水和耐热木材的可能性胶合时不会使木材脱色的胶; 44 cl,8 tbl,40 ex

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