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CATALYST AND METHOD OF PRODUCING HYDROCARBONS FROM CARBON MONOXIDE AND HYDROGEN (VERSIONS)

机译:由一氧化碳和氢气生产氢的催化剂和方法(版本)

摘要

FIELD: chemistry.;SUBSTANCE: invention relates to a method of producing hydrocarbons - paraffins and olefins (in form of gaseous, liquid and solid products) from reaction of CO with H2 (Fischer-Tropsch synthesis) and catalysts for this process. Described is a catalyst for synthesis of hydrocarbons from a mixture of carbon monoxide and hydrogen, containing a product of thermal treatment of the cobalt-aluminium hydroxo-nitrate-carbonate phase with a hydrotalcite-type layered structure or containing a phase of a product of thermal treatment of cobalt-aluminium hydroxo-nitrate-carbonate with a hydrotalcite-type layered structure at temperature 250-500°C in a current of inert gas or a mixture containing an inert gas and one or more of the following gases: oxygen, carbon monoxide, nitrogen oxide and hydrogen oxide. Described also are methods of producing hydrocarbons from synthetic gas using the catalysts described above.;EFFECT: use of disclosed catalysts in catalytic conversion of synthetic gas increases hydrocarbon output due to higher activity and selectivity of the catalyst.;9 cl, 11 ex, 2 tbl, 9 dwg
机译:技术领域:本发明涉及一种由CO与H 2 的反应(费托合成)生产烃-链烷烃和烯烃(以气态,液态和固态产物形式)的方法。和该过程的催化剂。描述了一种用于由一氧化碳和氢的混合物合成烃的催化剂,其包含具有水滑石型层状结构的钴-铝-羟基-硝酸-碳酸盐-碳酸酯相的热处理产物或包含其热产物的相。在惰性气体或含有惰性气体与以下一种或多种气体的混合物中,在250-500°C的温度下,用水滑石型层状结构处理氢氧化铝-碳酸氢钴铝,氧化氮和氧化氢。还描述了使用上述催化剂从合成气生产烃的方法。效果:由于催化剂的更高的活性和选择性,在合成气的催化转化中使用公开的催化剂增加了烃的输出。9 cl,11 ex,2 tbl,9 dwg

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