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METHOD OF DETERMINING CYSTEINE IN AQUEOUS SOLUTIONS VIA CYCLIC VOLTAMMETRY ON GRAPHITE ELECTRODE, MODIFIED BY COLLOIDAL GOLD PARTICLES

机译:胶体金颗粒修饰石墨电极上循环伏安法测定水溶液中的半胱氨酸

摘要

FIELD: chemistry.;SUBSTANCE: method of determining cysteine in aqueous solutions via cyclic voltammetry on a graphite electrode modified by colloidal gold particles according to the invention involves concentration of an electroactive compound on the surface of the electrode and obtaining an analytical signal by measuring potential, wherein the graphite electrodes are modified by colloidal gold particles, followed by detection of inverse peaks of electrooxidation of cysteine on the cathodic curve with potential sweep rate of 100 mV/s on a 0.1 M NaOH background solution; concentration of cysteien is determined from the value of maxima of current versus voltage curves in the potential range from minus 0.20 V to plus 0.10 V relative a saturated silver chloride electrode via a certified mixture addition technique.;EFFECT: more sensitive method of determining cysteine in aqueous solutions via cyclic voltammetry.;2 ex, 2 tbl, 2 dwg
机译:通过循环伏安法在根据本发明的胶体金颗粒改性的石墨电极上通过循环伏安法测定水溶液中的半胱氨酸的方法涉及在电极表面上浓缩电活性化合物并通过测量电势获得分析信号,其中通过胶体金颗粒修饰石墨电极,然后在0.1 M NaOH背景溶液中以100 mV / s的电位扫描速度在阴极曲线上检测半胱氨酸的电氧化反峰;半胱氨酸的浓度是通过经认证的混合物添加技术从相对于饱和氯化银电极的负0.20 V至正0.10 V的电位范围内的电流与电压曲线的最大值确定的;效果:更灵敏的测定半胱氨酸的方法循环伏安法测定水溶液; 2 ex,2 tbl,2 dwg

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