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Luminescent gold (III) compounds containing bidentate ligands for organic light elements and their manufacturing site

机译:包含用于有机发光元件的双齿配体的发光金(III)化合物及其制造场所

摘要

Embodiments of the invention are directed to luminescent gold (III) compounds which contain a bidentate ligand with at least one strong σ donor group, a process for the preparation of these compounds and the use of these compounds in organic lighting elements. The gold (III) compounds have the chemical structure: wherein: K is a nitrogen atom, Y is selected from a carbon or a nitrogen atom, AB is a substituted or unsubstituted cyclometalate ligand (for Y = C) or diimine ligand (for Y = N ), where A and B are cyclic structural derivatives, R1 and R2 are optionally substituted carbon donor ligands attached to the gold atom, provided that R1 and R2 are not -CH3, -CH2SiMe3, mesityl, pentafluorophenyl, -CH2C (O) R ', -CH (R) SO2CH (R) -, -C6H4N = NC6H5, and wherein R1 and R2 can optionally be combined to form a bidentate ligand, and n is greater than or equal to zero
机译:本发明的实施方案涉及包含具有至少一个强σ供体基团的双齿配体的发光金(III)化合物,这些化合物的制备方法以及这些化合物在有机照明元件中的用途。金(III)化合物具有以下化学结构:其中:K为氮原子,Y选自碳或氮原子,AB为取代或未取代的环金属盐配体(对于Y = C)或二亚胺配体(对于Y = N),其中A和B是环状结构衍生物,R1和R2是连接到金原子上的可选取代的碳供体配体,条件是R1和R2不是-CH3,-CH2SiMe3,三甲苯基,五氟苯基,-CH2C(O) R′,-CH(R),SO 2 CH(R)-,-C 6 H 4 N = NC 6 H 5,其中R 1和R 2可以任选地结合形成二齿配体,并且n大于或等于零。

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