New benzene derivative useful as surfactant, as surface-active medium, and as water repellent or oil repellent, preferably for surface modification of textiles, paper, glass, porous building materials or adsorbents

摘要

Benzene derivative (I), is new. Benzene derivative of formula (I), is new. R : (CH 2) mH or (CH 2) nR14; R14 : -CF 3, -OCF 3, -SCF 3, -SF 5, -OSF 5, -OC(CF 3) 3or -N=P(C oF 2o+1), C pF 2p+1, preferably -CF 3or -OCF 3; Y1 : O or S; m, n, o, p : 1-20, preferably 1-10; Z : -COO -M +, -SO 3-M +, -OSO 3-M +, -PO 32-M 2+, -OPO 32-M 26+, -NHSO 3-M +, -(OCH 2CH 2) qO -M +, -(OCH 2CH 2) q1O(CH 2) rCOO -M +, -(OCH 2CH 2) sO(CH 2) tSO 3-M +, -(OCH 2CH 2) uO(CH 2) vOSO 3-M +, -(OCH 2CH 2) wO(CH 2) xPO 32-M +2, -(OCH 2CH 2) yO(CH 2) aOPO 32-M 2+, -(CH 2) a1-N(R1R2R3) +X -, -(CH 2) a1-P(R4R5R6) +X -, pyridinium derivative of formula (II), quinolinium derivative of formula (III), isoquinolinium derivative of formula (IV), -OH, -(OCH 2CH 2) bOH, -O-(glycoside) c, preferably glucoside, diglucoside, triglucoside, -OCH 2CHOHCH 2OH, -(OCH 2CH 2) dOCH 2CHOHCH 2OH, -SO 2NR12 2, -(CH 2) eN(O)R12 2, -(CH 2) f-morpholine-N-oxide, -(OCH 2CH 2) g(OCH 2-phenyl) hNCO, -SiR7R8W1, -SiR9W1 2, COW1, -(OCH 2CH 2) iSO 2CH=CH 2, triazine derivative of formula (V), -(OCH 2CH 2) kOCOCR16=CH 2, -(OCH 2CH 2) k1OCH=CH 2, oxirane derivatives of formulae (VI) or (VII); M +H +, metal cation, preferably alkali metal cation or alkaline earth metal cation, preferably Li +, Na +, K +, NH 4+, Ca 2+or Zn 2+; q, q1, s, u, w, y : 1-1000; r, t, v, x, a : 1-3; R10 : H or -CH 3; X -Cl -, Br -, I -, CH 3SO 3-, CF 3SO 3-, methylphenyl-SO 3-or phenyl-SO 3-; R1-R6 : H, alkyl, aryl or benzyl; a1 : 0-3, preferably 0 or 1; either R12 : optionally substituted alkyl; or 2R12+N : heterocyclyl; b, d : 1-1000; c, e, f : 1-10; R7, R8, R9 : alkyl, aryl or benzyl, preferably CH 3; W1 : H, Cl, F, NR13 2, OR13 or N-imidazolyl; R11 : Cl or F; either R13 : optionally substituted alkyl; or 2R13+N : heterocycle; g, i, j : 0-1000; h : 0 or 1; R16 : H or alkyl, preferably H or CH 3; and k, k1, l, l1 : 0-100. Independent claims are also included for: (1) the preparation of (I); and (2) a composition comprising (I). [Image] [Image] [Image].