首页> 外国专利> Pre-refining and hydroconversion in fixed-bed of a heavy crude oil of hydrocarbons, comprises removing metals in hydrodemetallation section, hydrocracking at least part of the effluent, and fractionating a portion of the effluent

Pre-refining and hydroconversion in fixed-bed of a heavy crude oil of hydrocarbons, comprises removing metals in hydrodemetallation section, hydrocracking at least part of the effluent, and fractionating a portion of the effluent

机译:在固定床中对重质烃类原油进行预精炼和加氢转化,包括在加氢脱金属段中去除金属,对至少部分废水进行加氢裂化以及对一部分废水进行分馏

摘要

Pre-refining and hydroconversion in fixed-bed of a heavy crude oil of hydrocarbons containing at least 0.5 wt.% of asphaltenes, and more than 10 ppm weight of metal for producing a pre-refined synthetic crude, comprises: removing metals in a hydrodemetallation section including at least two permutable reactors; hydrocracking at least part of effluent at least partly demetallized in a hydrocracking section; fractionating at least one part of effluent in hydrocracked part and optionally hydrodesulfurized to obtain a light- and heavy- fraction; deasphalting heavy fraction; and recycling. Method of pre-refining and hydroconversion in fixed-bed of a heavy crude oil of hydrocarbons containing at least 0.5 wt.% of asphaltenes, and more than 10 ppm weight of metal for the production of a pre-refined synthetic crude, comprises: removing metals of the charge in a section of hydrodemetallation including at least two permutable reactors containing each one a catalyst of hydrodemetallation, where the reactors are placed in series to be used in a cyclic way consisting of the successive repetition of steps (b) and (c): (a) a step, in which the reactors are used all together for one length of time with most equal at the time, of desactivation and/or filling of the one of them, (b) a step during which at least one of reactors is shorted-circuit and the catalyst that it contains is regenerated and/or replaced by fresh or regenerated catalyst and during which the other permutable reactors are used, and (c) a step during which the reactors are used all together, the permutable reactor whose catalyst is regenerated and/or replaced during the preceding step being reconnected in a manner to downstream from the whole of the other permutable reactors, and the step being continued for one length of time with most equal at the time of desactivation and/or filling of one of the permutable reactors; hydrocracking at least part of the effluent at least partly demetallized in a section of hydrocracking containing at least a hydrocracking catalyst; optionally, at least one hydrodesulfurizing at least one portion of the effluent at least in hydrocracked part in a section of hydrodesulfurization containing at least a hydrodesulfurization catalyst; fractionating at least one portion of the effluent at least in hydrocracked part and optionally at least one hydrodesulfurized to obtain a light fraction and at least a heavy fraction; deasphalting the heavy fraction having a step of fractionation by a hydrocarbon solvent to obtain a de-asphalted fraction and a fraction rich in asphaltenes; and recycling at least portion of de-asphalted fraction at the step of hydrodemetallation, hydrocracking and/or hydrodesulfurization.
机译:用于生产预精制合成原油的重质原油的重质原油的预精制和加氢转化,所述重质原油包含至少0.5 wt。%的沥青质和10 ppm以上的金属,以生产预精制合成原油。包括至少两个置换电抗器的部分;在加氢裂化段中对至少部分废水进行至少部分脱金属的加氢裂化;在加氢裂化的部分中将至少一部分废水分馏并任选加氢脱硫以获得轻质和重质馏分;脱沥青重组分;和回收。在重质原油的固定床中进行预精制和加氢转化的方法,该重质原油包含至少0.5 wt。%的沥青质和10 ppm以上的金属重量的碳氢化合物,用于生产预精制的合成原油,包括:去除加氢脱金属部分中的装料金属,包括至少两个可置换反应器,每个反应器均包含一个加氢脱金属催化剂,其中反应器串联放置,以循环方式使用,包括连续重复步骤(b)和(c ):(a)停用和/或填充其中一个反应器的步骤,其中将所有反应器一起使用一整段时间,并且在当时最相等。短路反应器,并用新鲜的或再生的催化剂再生和/或替换其中所含的催化剂,在此期间使用其他可置换反应器,以及(c)将反应器一起使用的步骤反应堆其催化剂在前面的步骤中被再生和/或替换,以某种方式重新连接到整个其他可置换反应器的下游,并且该步骤持续一段时间,在失活和/或填充时最相等其中一个可置换反应堆;在含有至少一种加氢裂化催化剂的加氢裂化部分中将至少部分流出物的至少一部分进行加氢裂化;任选地,至少一种废水的至少一种加氢脱硫至少在加氢脱硫段中的加氢裂化部分中至少包含加氢脱硫催化剂;至少在加氢裂化的部分中分馏至少一部分流出物,并任选将至少一种加氢脱硫,以得到轻质馏分和至少重质馏分;将重馏分脱沥青,该重馏分具有通过烃溶剂分馏的步骤,以获得脱沥青的馏分和富含沥青质的馏分;在加氢脱金属,加氢裂化和/或加氢脱硫的步骤中,将至少一部分脱沥青馏分再循环。

著录项

  • 公开/公告号FR2970478A1

    专利类型

  • 公开/公告日2012-07-20

    原文格式PDF

  • 申请/专利权人 IFP ENERGIES NOUVELLES;

    申请/专利号FR20110000138

  • 发明设计人 GUIBARD ISABELLE;QUIGNARD ALAIN;

    申请日2011-01-18

  • 分类号C10G67/04;B01J8/04;C10G21/14;C10G45/08;C10G47/16;

  • 国家 FR

  • 入库时间 2022-08-21 17:04:04

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