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TUNGSTEN COMPLEX, METATHESIS REACTION CATALYST, AND METHOD FOR PRODUCING CYCLIC OLEFIN RING-OPENING POLYMER

机译:钨络合物,分解反应催化剂和制备环状烯烃开环聚合物的方法

摘要

PROBLEM TO BE SOLVED: To provide a tungsten complex which is useful as a component of a catalyst for achieving well-controlled polymerization for example in ring-opening metathesis polymerization of a cyclic olefin compound, and to provide a metathesis reaction catalyst including the tungsten complex.;SOLUTION: The tungsten complex is represented by formula (1) (wherein each of R1 and R2 is independently a group selected from a 1-24C alkyl group optionally including a substituent and a 6-24C aryl group optionally including a substituent, R1 and R2 may optionally be bonded together so as to form an alicyclic structure, each of Xs independently is a ligand selected from a halogen atom, an aryloxy ligand, an alkoxy ligand, and an alkyl ligand, and n is an integer of 1 to 3).;COPYRIGHT: (C)2013,JPO&INPIT
机译:解决的问题:提供一种钨络合物,其用作实现良好控制的聚合反应的催化剂组分,例如在环烯烃化合物的开环易位聚合中,并提供包括该钨络合物的易位反应催化剂解决方案:钨配合物由式(1)表示(其中R 1 和R 2 各自独立地是选自1-24C烷基的基团包含取代基和任选包含取代基的6-24C芳基的R Sup> 1 和R 2 可任选地结合在一起形成脂环结构,每个X独立地是选自卤素原子,芳氧基配体,烷氧基配体和烷基配体的配体,并且n是1至3的整数。);版权所有:(C)2013,JPO&INPIT

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