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Lower hydrocarbon aromatic compound catalyst, aromatic compound using lower hydrocarbon as raw material, and method for producing hydrogen

机译:低级烃芳族化合物催化剂,以低级烃为原料的芳族化合物及其制氢方法

摘要

P To provide an aromatization catalyst for producing an aromatic compound such as benzene, naphthalene and etc. as well as hydrogen gas by using a lower hydrocarbon such as natural gas or the like and their production method. PSOLUTION: A catalyst comprising a catalytic material, which contains Re or one or more of its compounds as an indispensable component and, if necessary, Zn, Ga, Co, Fe or one or more of their compounds and a metallosilicate is used. In the presence of the catalyst and co-presence of carbon monoxide and/or carbon dioxide and an aromatic compound and hydrogen are produced by using a lower hydrocarbon as a raw material. An aromatic hydrocarbon such as benzene, toluene, xylene, naphthalene and etc. and hydrogen are efficiently produced. Also, if reaction is carried out in the co-presence of carbon monoxide and/or carbon dioxide, the reaction conversion efficiency is improved and further and decrease of the production speed with the lapse of time is suppressed and thus stable capability for a long duration can be obtained. PCOPYRIGHT: (C)2011 and JPO& INPIT
机译:

提供一种芳香化催化剂,其用于通过使用诸如天然气等的低级烃来生产诸如苯,萘等的芳族化合物以及氢气。

解决方案:使用包含催化材料的催化剂,该催化剂包含Re或其一种或多种化合物作为必不可少的成分,并且如果需要,可使用Zn,Ga,Co,Fe或它们的一种或多种化合物以及金属硅酸盐。在催化剂的存在下,通过使用低级烃作为原料来生产一氧化碳和/或二氧化碳与芳族化合物和氢的共存。有效地生产了苯,甲苯,二甲苯,萘等芳族烃和氢气。而且,如果在一氧化碳和/或二氧化碳的共存下进行反应,则反应转化效率提高,并且进一步抑制了随着时间的流逝生产速度的降低,因此长期稳定的能力。可以获得。

版权:(C)2011和JPO&INPIT

著录项

  • 公开/公告号JP5283665B2

    专利类型

  • 公开/公告日2013-09-04

    原文格式PDF

  • 申请/专利权人 市川 勝;株式会社日本製鋼所;

    申请/专利号JP20100152001

  • 发明设计人 市川 勝;大西 隆一郎;

    申请日2010-07-02

  • 分类号B01J29/48;C01B3/40;C07C15/04;C07C15/24;C07C2/88;C07B61;

  • 国家 JP

  • 入库时间 2022-08-21 16:54:34

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