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AQUEOUS RADIATION-CURABLE EPOXY ACRYLATE DISPERSIONS

机译:水性辐射固化环氧丙烯酸酯分散体

摘要

The invention relates to aqueous radiation-hardenable epoxy acrylate dispersions comprising (a) an epoxy acrylate resin (P*) with at least two acrylate groups per molecule, wherein at 25 degrees Celsius, said epoxy acrylate resin is not self-disperging in water; and (b) a dispergator (D*) with at least one acrylate group per molecule, wherein said dispersions can be produced by converting, in a first step (i), in the presence of a catalyst if need be, one or several compounds (A) selected from the group of non-ionic compounds having a HLB value of less than 12, and containing at least two oxirane groups per molecule, with one or several compounds (B) selected from the group of non-ionic compounds having a HLB value in the range from 12 to 20, and which contain at least one h-acid group (ZH) per molecule. The compounds (A) and (B) are employed at an equivalence ratio EpO (A):ZH (B) in the range from 1.3:1 to 400:1, and in a second step (ii), the reactive mixture thus obtained is converted, in the presence of a catalyst if need be, with one or several non-ionic compounds having a HLB value of less than 12, and containing at least two oxirane groups per molecule (compounds A), and with one or several compounds (C) selected from the group of non-ionic compounds having a HLB value of less than 12, and which contain at least two H-acid groups. The compounds (A) and (C) are employed at an equivalence ratio EpO (A):ZH (C) in the range from 1.1:1 to 20:1. In a third step (iii), the reactive mixture thus obtained is converted, in the presence of a catalyst if need be, with acrylic acid by ring opening of all epoxy groups. In a fourth step (iv), the reactive mixture thus obtained is disperged in water.
机译:本发明涉及可辐射固化的水性丙烯酸丙烯酸酯分散体,其包含:(a)每个分子具有至少两个丙烯酸酯基的环氧丙烯酸酯树脂(P *),其中在25摄氏度下,所述环氧丙烯酸酯树脂不自分散在水中; (b)每分子具有至少一个丙烯酸酯基的分散剂(D *),其中所述分散体可以通过在第一步(i)中,如果需要的话,在催化剂的存在下,将一种或几种化合物转化而制得(A)选自HLB值小于12的非离子化合物,每分子至少包含两个环氧乙烷基,一种或几种化合物(B)选自具有以下特征的非离子化合物: HLB值在12至20的范围内,并且每个分子包含至少一个h-酸基团(ZH)。以1.3:1至400:1的当量比EpO(A):ZH(B)使用化合物(A)和(B),并且在第二步骤(ii)中,如此获得反应性混合物在一种催化剂的存在下(如果需要)与一种或几种HLB值小于12,每分子至少含有两个环氧乙烷基团的非离子化合物(化合物A)以及一种或几种化合物进行转化(C)选自HLB值小于12且包含至少两个H-酸基团的非离子化合物。化合物(A)和(C)以当量比EpO(A)∶ZH(C)以1.1∶1至20∶1的范围使用。在第三步骤(iii)中,如果需要,在催化剂的存在下,通过所有环氧基的开环将如此获得的反应混合物转化为丙烯酸。在第四步骤(iv)中,将如此获得的反应混合物分散在水中。

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