POLYOXYALKYLENE POLYOL, POLYMER-DISPERSED POLYOL, FLEXIBLE POLYURETHANE FOAM AND PRODUCTION PROCESS THEREOF

摘要

To provide a process for producing a polyoxyalkylene polyol having a high primary hydroxylation rate of the terminal hydroxyl groups, in spite of a low degree of total unsaturation and a low content of oxyethylene groups.;A process for producing a polyoxyalkylene polyol, which comprises: a first polymerization step of subjecting an alkylene oxide to ring-opening addition polymerization to an initiator in the presence of a DMC catalyst (a1) to obtain a first intermediate polyol; a second polymerization step of subjecting, propylene oxide to ring-opening addition polymerization in the presence of a polymerization catalyst (a2) made of an alkali metal hydroxide and/or an alkali metal alcoholate compound to obtain a second intermediate polyol; and a third polymerization step of subjecting, ethylene oxide to ring-opening addition polymerization in the presence of a polymerization catalyst (a2) to obtain a polyoxyalkylene polyol (A1).