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Polyvinylidene fluoride resin expanded beads, and molded articles of polyvinylidene fluoride resin expanded beads

机译:聚偏二氟乙烯树脂发泡珠,聚偏二氟乙烯树脂发泡珠的成型品

摘要

Provided are polyvinylidene fluoride resin expanded beads which can be molded by in-mold molding and thus stably provide, without impairing excellent characteristics inherent in polyvinylidene fluoride resin, molded articles having excellent mechanical properties. Polyvinylidene fluoride resin expanded beads, characterized in that when 1 to 3 mg of the expanded beads are subjected to heat-flux type differential scanning calorimetry (DSC) wherein the beads are heated from 25° C. to 200° C. at a temperature rise rate of 10° C./min, the obtained DSC curve (of first heating) has both an inherent endothermic peak which is inherent in polyvinylidene fluoride resin and one or more higher-temperature endothermic peaks which appear on the higher-temperature side of the inherent endothermic peak, the quantity of heat of melting of the higher-temperature endothermic peaks being at least 0.5 J/g.
机译:本发明提供一种聚偏二氟乙烯系树脂发泡珠,其可以通过模内成型而成型,因此在不损害聚偏二氟乙烯系树脂固有的优异特性的情况下,能够稳定地提供机械特性优异的成型品。聚偏二氟乙烯树脂发泡珠粒,其特征在于,当将1-3mg的发泡珠粒进行热通量型差示扫描量热法(DSC)时,在温度升高的情况下将珠粒从25℃加热至200℃。以10℃/ min的速率,获得的(第一次加热的)DSC曲线既具有聚偏二氟乙烯树脂固有的固有吸热峰,又具有出现在其高温侧的一个或多个高温吸热峰。固有吸热峰,高温吸热峰的熔化热量至少为0.5 J / g。

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