Cp-ZxA-Zy (I)wherein Z is a bisphenyl sulfone moiety of formula: (II):; A is a phthalazinone moiety of formula (III):; Cp is A, as defined above, or a biphenol moiety of formula (IV):; x is an integer of at least 1;y is an integer of at least 1; and x+y=n, where n is an integer such that the polymer has a weight average molecular weight of about 20,000 to about 170,000, the composition comprising less than 5%, by weight, of low molecular weight oligomers; and having a glass transition temperature (Tg) from 225 to 305° C."/>
High temperature poly(aryl ether)s containing a phthalazinone moiety
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High temperature poly(aryl ether)s containing a phthalazinone moiety
High temperature poly(aryl ether)s containing a phthalazinone moiety
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机译:含有酞嗪酮部分的高温聚(芳基醚)
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摘要
A poly(phthalazinone sulfone) composition for molded articles having such characteristics as high temperature resistance, good electrical properties, good chemical and solvent resistance and toughness consists essentially of a polymer of formula (I):Cp-ZxA-Zy (I)wherein Z is a bisphenyl sulfone moiety of formula: (II):; A is a phthalazinone moiety of formula (III):; Cp is A, as defined above, or a biphenol moiety of formula (IV):; x is an integer of at least 1;y is an integer of at least 1; and x+y=n, where n is an integer such that the polymer has a weight average molecular weight of about 20,000 to about 170,000, the composition comprising less than 5%, by weight, of low molecular weight oligomers; and having a glass transition temperature (Tg) from 225 to 305° C.
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机译:具有诸如耐高温性,良好的电性能,良好的耐化学性和耐溶剂性以及韧性的特性的用于模塑制品的聚(酞嗪酮砜)组合物基本上由式(I)的聚合物组成:<?in-line-formulae description =“ In-line Formulae” end =“ lead”?> <图像alt =“私人使用字符Parenopenst” file =“ US08501896-20130806-PARENOPENST.GIF” he =“ 7.20mm” id =“ PRIVATE-USE-CHARACTER-00001” imgContent =“字符” imgFormat =“ GIF” wi =“ 8.47mm” /> Cp-Z <图像alt =“私人使用字符Parenclosest” file =“ US08501896-20130806-PARENCLOSEST。 GIF“ he =” 7.20mm“ id =” PRIVATE-USE-CHARACTER-00002“ imgContent =”字符“ imgFormat =” GIF“ wi =” 8.47mm“ /> x Sub> AZ <图像alt =“私人使用字符Parenclosest” file =“ US08501896-20130806-PARENCLOSEST.GIF” he =“ 7.20mm” id =“ PRIVATE-USE-CHARACTER-00004” imgContent =“字符” imgFormat =“ GIF” wi =“ 8.47mm” /> y Sub>(I)<?in-line-formulae description =“在线公式” end =“ tail”?>其中Z是式(II)的双苯基砜部分:; 化学>A是式(III)的酞嗪酮部分:; 化学>Cp为如上定义的A或式(IV)的双酚部分:; 化学>x为至少1的整数;y是至少1的整数; x + y = n,其中n是使得聚合物具有约20,000至约170,000的重均分子量的整数,该组合物包含按重量计小于5%的低分子量低聚物;且玻璃化转变温度(Tg)为225至305℃。
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