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Platinum group metal-free catalysts for reducing the ignition temperature of particulates on a diesel particulate filter

机译:不含铂族金属的催化剂,可降低柴油机微粒过滤器上微粒的着火温度

摘要

A catalyzed diesel particulate filter (CDPF) and a method for filtering particulates from diesel engine exhaust are provided, where the catalyzed diesel particulate filter includes a substrate and a catalyst composition, where the catalyst composition contains at least one first component, at least one second component, and at least one third component, where the first component is at least one first component selected from the group consisting of cerium and a lanthanide and mixtures thereof, the at least one second component is selected from the group consisting of cobalt, copper, manganese and mixtures thereof; and the third component comprises strontium, where the first component, the second component, and the third component are in an oxide form after calcination. The catalyst on the catalyzed diesel particulate filter lowers the temperature at which particulates are removed from the CDPF by oxidizing the particulates on the filter. The catalyzed diesel particulate filter may also include a washcoat. Washcoats prepared from colloidal aluminum oxide may have higher surface areas and pore volumes loadings than washcoats containing aluminum oxide prepared from aluminum nitrate.
机译:提供了催化的柴油机微粒过滤器(CDPF)和从柴油机排气中过滤微粒的方法,其中催化的柴油机微粒过滤器包括基质和催化剂组合物,其中该催化剂组合物包含至少一种第一组分,至少一个第二组分。组分和至少一种第三组分,其中第一组分是选自铈和镧系元素及其混合物的至少一种第一组分,至少一种第二组分选自钴,铜,锰及其混合物;所述第三组分为锶,所述第一组分,第二组分和第三组分在煅烧后为氧化物形式。催化的柴油机微粒过滤器上的催化剂通过氧化过滤器上的微粒,降低了从CDPF中除去微粒的温度。催化柴油机微粒过滤器还可包括修补基面涂层。由胶态氧化铝制备的修补基面涂料比由硝酸铝制备的含有氧化铝的修补基面涂料具有更高的表面积和孔体积载荷。

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