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Method for providing toughened poly(trimethylene terephthalate) molding resins

机译:提供增韧的聚对苯二甲酸丙二醇酯成型树脂的方法

摘要

Disclosed is a method including (A) melt blending first components including (a-1) a poly(trimethylene terephthalate) homopolymer or copolymer resin; and (a-2) one or more ionomer polymers or a combination of one or more ionomer polymers and acid polymers; to provide a first melt blend; and (B) melt blending said first melt blend with one or more Group B polymeric toughener(s) selected from the group consisting of an ethylene copolymers of the formula E/X/Y wherein:E is the radical formed from ethylene;X is selected from the group consisting of radicals formed fromCH2═CH(R1)—C(O)—OR2 Y is one or more radicals formed from selected monomers with the proviso that Y must include at least one radical formed from monomers selected from the group consisting of maleic anhydride, (meth)acrylic acid, maleic acid, maleic acid monoesters, itaconic acid, fumaric acid, fumaric acid monoesters, salts of said preceding acids, and glycidyl acrylate, glycidyl methacrylate, and glycidyl vinyl ether.
机译:公开了一种方法,该方法包括:(A)熔融共混包括(a-1)聚对苯二甲酸丙二醇酯均聚物或共聚物树脂的第一组分; (a-2)一种或多种离聚物聚合物或一种或多种离聚物聚合物与酸聚合物的组合;提供第一熔体混合物; (B)将所述第一熔体共混物与一种或多种选自式E / X / Y的乙烯共聚物的B类聚合物增韧剂熔融共混,其中: E是由乙烯形成的基团; X选自由下列基团组成的基团:<?in-line-formulae description =“ In-line Formulae” end =“ lead”?> CH 2 ═CH(R 1 )-C(O)- OR 2 <?in-line-formulae description =“ In-line Formulae” end =“ tail”?> Y是由选择的单体形成的一个或多个基团,条件是Y必须包括至少一个由选自马来酸酐,(甲基)丙烯酸,马来酸,马来酸单酯,衣康酸,富马酸的单体形成的基团。酸,富马酸单酯,上述酸的盐以及丙烯酸缩水甘油酯,甲基丙烯酸缩水甘油酯和缩水甘油基乙烯基醚。

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