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CARBON BASED DIAZENIUMDIOLATE NITRIC OXIDE-RLEASING POLYMER COMPOSITION.
CARBON BASED DIAZENIUMDIOLATE NITRIC OXIDE-RLEASING POLYMER COMPOSITION.
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机译:碳基重氮二氧化氮释放型聚合物组成。
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摘要
A composition comprising a carbon-bound diazeniumdiolate attached to at least one phenyl-containing polymer, and having the formula R3 -C(R )x(N2O2R )y, wherein x is an integer from 0 to 2 and y is an integer from 1 to 3, and the sum of x plus y equals 3; wherein R1 is selected from the group consisting of an electron withdrawing group, a cyano group, an ether, a thioether, and a non-enamine amine; wherein R2 is selected from the group consisting of a countercation and a protecting group on a terminal oxygen; and wherein R is a phenyl of said phenyl-containing polymer, and said phenyl is either pendant from the backbone of said polymer or part of the backbone of said polymer.
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机译:一种组合物,其包含与至少一种含苯基的聚合物连接的碳键合的二氮杂二氮烯鎓盐,并且具有式R 3 -C(R)x(N 2 O 2 R)y,其中x是0至2的整数,y是1的整数到3,x和y的和等于3;其中R1选自吸电子基团,氰基,醚,硫醚和非烯胺。其中R2选自由抗衡阳离子和末端氧上的保护基组成的组;其中R是所述含苯基聚合物的苯基,并且所述苯基是所述聚合物主链的侧基或所述聚合物主链的一部分。
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