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SURFACE WATER AND DRINKING WATER QUALITY EVALUATION PROCESS

机译:地表水和饮用水水质评价过程

摘要

The invention relates to a process and a system for in-situ evaluation of surface water and drinking water quality. According to the invention, the process consists in measuring the UV absorbance of a sample, at a wave length of 300 nm, and, in case the absorbance exceeds a value of 0.5, the sample is diluted and a further absorbance measurement is performed while, in case the value is lower than 0.5, there is analyzed the intrinsic fluorescence of the compounds in the dissolved organic matter, the amino acids tryptophan (T) and tyrosine (B) and the humic acid (A) which are representative for the quality of surface water and drinking water, as well as the signal due to Raman scattering (R) on water molecules, there being determined the intensity ratios between the tryptophane-related maximum value and the Raman signal-related maximum value (T/R), between the tryptophane-related maximum value and the humic acid-related maximum value (T/A) and between the tyrosine-related maximum value and the tryptophane-related maximum value (B/T), based on which the water sample shall fall in a certain quality class. The system claimed by the invention consists of a radiation source (2) in the UV-Vis range for analyzing the absorbance of the test sample, which uses an optical fibre (5) for transmitting the radiation to the sample placed in a support of a tank (6) provided with an optical filter (7) and a source (1) of electromagnetic radiation in a wave length of 266 nm, employed for the fluorescent excitation of the test samples, which transmits the electromagnetic radiation, via another optical fiber, to the sample placed within the tank (6), while a third optical fiber (8) leads from the tank to a spectrophotometer (3) used for recording the absorbance spectra and fluorescence spectra, respectively, which is connected to a portable computer (4).
机译:本发明涉及用于原位评价地表水和饮用水水质的方法和系统。根据本发明,该方法包括在波长为300 nm的波长下测量样品的UV吸光度,并且如果吸光度超过0.5,则将样品稀释并进行进一步的吸光度测量,如果该值低于0.5,则分析化合物在溶解的有机物,代表其质量的氨基酸色氨酸(T)和酪氨酸(B)和腐殖酸(A)中的固有荧光。地表水和饮用水以及水分子上的拉曼散射(R)引起的信号,确定了色氨酸相关最大值与拉曼信号相关最大值(T / R)之间的强度比。色氨酸相关最大值和腐殖酸相关最大值(T / A)以及酪氨酸相关最大值和色氨酸相关最大值(B / T)之间,水样应基于一定质量的分类s。本发明要求保护的系统由紫外-可见光范围内的辐射源(2)组成,用于分析测试样品的吸光度,该系统使用光纤(5)将辐射传输至放置在支撑架上的样品。罐(6)装有滤光器(7)和波长为266 nm的电磁辐射源(1),用于测试样品的荧光激发,并通过另一根光纤传输电磁辐射,到放置在水箱(6)内的样品上,第三根光纤(8)从水箱通向分光光度计(3),用于分别记录吸收光谱和荧光光谱,并与便携式计算机(4)连接)。

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