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OPTICAL REFRACTIVE INDEX-MODIFYING POLYMER COMPOSITION, HOLOGRAPHIC RECORDING MATERIAL AND METHOD OF CONTROLLING REFRACTIVE INDEX

机译:光学折射率改性聚合物组合物,全息记录材料和折射率控制方法

摘要

The present invention provides an optical refractive index-modifying polymer composition which can efficiently modulate (change) refractive index upon light irradiation, and exhibits such high storage stability that the once modulated refractive index does not substantially change anymore upon time elapse, and the optical refractive index-modifying polymer composition comprises as a main component a polymer (A) which is a polymer of monomers including an acrylic vinyl monomer represented by the following formula (1):        CH2=C (R1)-C (=O) O-R2=CH2     (1)wherein R1 represents a hydrogen atom or a methyl group, R2 represents a saturated or unsaturated hydrocarbon group having 1 to 20 carbon atoms, and the molecule may contain a hetero atom or a halogen atom, as an essential component and contains a remaining radical-polymerizable side-chain vinyl group in the molecule, wherein the composition comprises a thermally curable polymer (B) in an amount of 5 to 60 parts by weight per 100 parts by weight of the polymer (A).
机译:本发明提供了一种光学折射率改性聚合物组合物,其可以在光照射下有效地调制(改变)折射率,并且显示出如此高的存储稳定性,以至于一旦经过调制的折射率基本上不会随着时间的流逝而变化,折射率改性聚合物组合物包含作为主要成分的聚合物(A),该聚合物是包括由下式(1)表示的丙烯酸乙烯基单体的单体的聚合物:CH 2 = C(R 1 )-C(= O)O-R 2 = CH 2 (1)其中R 1 代表氢原子或甲基,R 2 代表具有1至20个碳原子的饱和或不饱和烃基,并且分子可以包含杂原子或卤素原子作为基本成分,并且在分子中包含残留的可自由基聚合的侧链乙烯基,其中,组合物包含相对于每100重量份为5至60重量份的热固性聚合物(B)聚合物(A)的重量。

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