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SYSTEM AND PROCESS FOR DETERMINING AND ANALYSING SURFACE PROPERTY PARAMETERS OF SUBSTANCE BASED ON KINETIC METHOD

机译:基于动力学方法的物质表面特性参数测定与分析系统及过程

摘要

A system and a process for determining and analysing surface property parameters of a substance based on a kinetic method. The system comprises a sample treatment system including a reactor (3), a collector for the liquid to be tested (5) and a container for the liquid to be tested (6), and a detection system including detecting electrodes (13), an operator for concentration and activity, a processor for kinetic data, an operating module for surface properties and a results outputting module. The method treats the substance to be tested with an electrolyte solution, measures the activity of the liquid to be tested after the reaction at a pre-set interval, and processes the data with the processor for kinetic data and the operating module for surface properties, so as to obtain the surface property parameters of the substance to be tested. The present invention employs a kinetic method of ion exchange to overcome the difficulties in the test procedure of having a long reaction equilibrium time, and the difficulty in determining the equilibrium and calibrating the value of m accurately. The five parameters representing the surface properties of a substance can be calculated from only two parameters, i.e. the intercept and gradient of the linear regression equation obtained from the kinetic data, and the total amount of charge on the surface can also be determined directly.
机译:基于动力学方法确定和分析物质的表面特性参数的系统和过程。该系统包括样品处理系统,其包括反应器(3),用于待测液体的收集器(5)和用于待测液体的容器(6),以及包括检测电极(13),用于集中和活动的操作员,用于动力学数据的处理器,用于表面性质的操作模块和结果输出模块。该方法用电解质溶液处理待测物质,以预设的间隔测量待测液体在反应后的活性,并用处理器处理动力学数据和操作模块处理表面性质,以获得待测物质的表面性能参数。本发明采用离子交换的动力学方法,克服了反应平衡时间长的测试过程中的困难,以及难以确定平衡和准确地校正m值的困难。只能从两个参数计算代表物质表面性质的五个参数,即从动力学数据获得的线性回归方程的截距和梯度,并且还可以直接确定表面上的电荷总量。

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