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naphthalene amidine imide

机译:萘am酰亚胺

摘要

To be naphthalene amidine imide is described in the formula (1): ; (1) in the ; style ; R 1 , R 2 , R 3 , R 4 , R 5 and R 6 is independently hydrogen; Or C 1 -C 37 alkyl; The ; - C 1 -C 37 alkyl CH 2 1 to 10 of the units are independently carbonyl carbonyl group; Oxygen atom; Sulfur; Selenium atoms; Tellurium atoms; cis - or trans -CH = CH- group; C C- acetylenic group; 1,2-, 1,3- or 1,4-substituted phenyl radicals; 2,3, 2,4, 2,5, 2,6, 3,4 or 3,5-disubstituted pyridine radical; 2,3, 2,4, 2,5 or 3,4-disubstituted thiophene radicals; 1,2, 1,3, 1,4, 1,5, 1,6, 1,7, 1,8, 2,3, 2,6 or 2,7-di 1,2, 1,3, 1,4, 1,5, 1,6, 1,7, 1,8, 1,9, 1,10, 2,3 , 2,6, 2,7, 2,9, can be optionally substituted with 2,10- or 9,10-disubstituted anthracene radicals; CH = CH- group, one or two of the naphthalene radicals and the anthracene radicals CH- group may be substituted by a nitrogen atom; ; - CH 2 - single hydrogen atom of the group is 12 or less from the same carbon atom, independently of each other fluorine; Chlorine; Bromine; Or iodine; Cyano group; Linear alkyl chain carbon atoms with more than 18; cis - or trans -CH = CH- group; C C- acetylenic group; 1,2-, 1,3- or 1,4-substituted phenyl radicals; 2,3, 2,4, 2,5, 2,6, 3,4 or 3,5-disubstituted pyridine radical; 2,3, 2,4, 2,5 or 3,4-disubstituted thiophene radicals; 1,2, 1,3, 1,4, 1,5, 1,6, 1,7, 1,8, 2,3, 2,6 or 2,7-di naphthalene radical; 1,2, 1,3, 1,4, 1,5, 1,6, 1,7, 1,8, 1,9, 1,10, 2,3, 2,6, 2,7, 2,9, and may be substituted by a 2,10- or 9,10-disubstituted anthracene radicals; Less than six in the alkyl chain CH 2 - unit are independently a carbonyl group, an oxygen atom, a sulfur atom, a selenium atom, the alkyl radical may also be substituted by a tellurium atom CH 2 - single hydrogen atom of the group is 12 or fewer fluorine atoms at the same C- independently of one another, chlorine, bromine or iodine or cyano groups or substituted by a linear alkyl chain having less than 18 carbon atoms, may be, where 1 to 6 CH 2 - unit are independently a carbonyl group, an oxygen atom, a sulfur atom, a selenium atom, a tellurium atom, cis - or trans -CH = CH- may be substituted by, one unit may be replaced by a nitrogen atom CH-, acetylenic C C- group, 1,2-, 1,3- or 1,4 -substituted phenyl radicals, 2,3-, 2,4-, 2,5-, 2,6-, 3,4- or 3,5-disubstituted pyridine radicals, 2,3-, 2,4-, 2,5- or 3,4-disubstituted thiophene radicals, 1,2-, 1,3-, 1,4-, 1,5, 1,6, 1,7, 1,8, 2,3-, 2,6- or 2,7-disubstituted naphthalene radicals can be optionally substituted with 1 or 2 carbon atoms by nitrogen atoms sleeping, 1,2, 1,3, 1,4- , 1,5, 1,6, 1,7, 1,8, 1,9, 1,10, 2,3, 2,6, 2,7, 2,9 , 2,10- or may be substituted by a 9,10-disubstituted anthracene radicals, 1 or 2 The carbon may be replaced by a nitrogen atom; Or ; Instead of methine substituent-free way or quaternary carbon atoms, linked fulfill the pair form a ring such as cyclohexane ring, or; Or R 1 and R 2 is a carbon atom C 1 and C 2 and combined book or R 3 When and R 4 is a carbon atom C 3 and C 4 and combined to form a six-membered radical, an amino radical, ; ; R 7 and R 8 = O, or independently from each other; Or a nitrogen atom = NH- N 1 (R 6 In the case of) a combined or nitrogen atom N 2 (R 7 In the case of ) and combined to form a five-membered radical = NH- being. ; This compound has a different purpose, and preferably it is useful as UV absorbers in cosmetics.
机译:在式(1)中描述了萘am酰亚胺: (1)中;风格; R 1 ,R 2 ,R 3 ,R 4 ,R 5 和R 6 独立地为氢;或C 1 -C 37 烷基;的; -C 1 -C 37 烷基CH 2 1至10个单元独立地为羰基羰基;氧原子硫;硒原子;碲原子; 顺式 -或反式 -CH = CH-基团; C C-炔基; 1,2-,1,3-或1,4-取代的苯基; 2,3,2,4,2,5,2,6,3,4或3,5-二取代的吡啶基; 2,3,2,4,2,5或3,4-二取代的噻吩基; 1,2,1,3,1,4,1,5,1,6,1,7,1,8,2,3,2,6或2,7-di 1,2,1,3,1 ,4,1,5,1,6,1,7,1,8,1,9,1,10,2,3,2,6,2,7,2,9可以可选地被2, 10-或9,10-二取代的蒽基; CH = CH-基,萘基和蒽基中的一个或两个可以被氮原子取代; ; -CH 2 -该基团中的单个氢原子与相同的碳原子相互独立地小于或等于12;氯;溴;或碘氰基集团;直链烷基碳原子数大于18; 顺式 -或反式 -CH = CH-基团; C C-炔基; 1,2-,1,3-或1,4-取代的苯基; 2,3,2,4,2,5,2,6,3,4或3,5-二取代的吡啶基; 2,3,2,4,2,5或3,4-二取代的噻吩基; 1,2,1,3,1,4,1,5,1,6,1,7,1,8,2,3,2,6或2,7-二萘基; 1,2,1,3,1,4,1,5,1,6,1,7,1,8,1,9,1,10,2,3,2,6,2,7,2, 9,并且可以被2,10-或9,10-二取代的蒽基取代;烷基链CH 2 -单元中少于六个的独立地是羰基,氧原子,硫原子,硒原子,烷基也可以被碲原子CH 2 -该基团的单个氢原子在同一C原子上为12个或更少的氟原子-彼此独立地为氯,溴或碘或氰基,或被碳原子数少于18的线性烷基链取代,其中1至6个CH 2 -单元独立地是羰基,氧原子,硫原子,硒原子,碲原子,顺式 < I>-或反式 -CH = CH-可以被一个氮原子CH-,炔属C C-基团,1,2-,1,3-或1,4取代-取代的苯基,2,3-,2,4-,2,5-,2,6-,3,4-或3,5-二取代的吡啶基,2,3-,2,4-,2 5-或3,4-二取代的噻吩基团,1,2-,1,3-,1,4-,1,5,1,6,1,7,1,8,2,3-,2,6 -或2,7-二取代的萘基可以任选被1或2个碳原子所取代的氮原子睡觉,1,2,1,3,1,4-,1,5,1,6,1,7,1,8,1,9,1, 10、2、3、2,6、2,7、2,9、2,10-或可被9,10-二取代的蒽基1或2取代。碳原子可被氮原子取代;要么 ;取代无次甲基取代基的方式或季碳原子,连接成对形成一个环,例如环己烷环,或或R 1 和R 2 是碳原子C 1 和C 2 以及碳原子或R 3当和R 4 是碳原子C 3 和C 4 并结合形成六元基团时,氨基; ; R 7 和R 8 = O,或彼此独立;或氮原子= NH- N 1 (在情况下为R 6 )组合或氮原子N 2 (R 7 在的情况下,合并形成一个五元自由基= NH-。 ;该化合物具有不同的用途,并且优选用作化妆品中的紫外线吸收剂。

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